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Titolo:
The use of borane-amine adducts as versatile palladium-catalyzed hydrogen-transfer reagents in methanol
Autore:
Couturier, M; Andresen, BM; Tucker, JL; Dube, P; Brenek, SJ; Negri, JT;
Indirizzi:
Pfizer Inc, Global Res & Dev, Chem Res & Dev, Groton, CT 06340 USA Pfizer Inc Groton CT USA 06340 Dev, Chem Res & Dev, Groton, CT 06340 USA
Titolo Testata:
TETRAHEDRON LETTERS
fascicolo: 15, volume: 42, anno: 2001,
pagine: 2763 - 2766
SICI:
0040-4039(20010409)42:15<2763:TUOBAA>2.0.ZU;2-1
Fonte:
ISI
Lingua:
ENG
Soggetto:
MOLECULAR ADDITION-COMPOUNDS; REDUCTION;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Life Sciences
Physical, Chemical & Earth Sciences
Citazioni:
25
Recensione:
Indirizzi per estratti:
Indirizzo: Couturier, M Pfizer Inc, Global Res & Dev, Chem Res & Dev, Eastern Point Rd,POB 8013, Groton, CT 06340 USA Pfizer Inc Eastern Point Rd,POB 8013 Groton CT USA 06340 USA
Citazione:
M. Couturier et al., "The use of borane-amine adducts as versatile palladium-catalyzed hydrogen-transfer reagents in methanol", TETRAHEDR L, 42(15), 2001, pp. 2763-2766

Abstract

The scope of borane-amine adducts as reducing agents is broadened through palladium-catalyzed methanolysis capable of reducing a wide variety of functional groups. Hence, borane mediated reduction of a benzamide followed by a tandem methanolysis/hydrogenolysis of the resulting borane-benzylamine adduct allows chemoselective removal of an N-benzoyl in the presence of an O-benzoyl. (C) 2001 Elsevier Science Ltd. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 26/09/20 alle ore 05:28:13