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Titolo:
Iodosobenzene and iodoxybenzene as reagents for oxygen transfer in organophosphorus chemistry
Autore:
Mielniczak, G; Lopusinski, A;
Indirizzi:
Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland Polish Acad Sci Lodz Poland PL-90363 omol Studies, PL-90363 Lodz, Poland
Titolo Testata:
SYNLETT
fascicolo: 4, , anno: 2001,
pagine: 505 - 508
SICI:
0936-5214(200104):4<505:IAIARF>2.0.ZU;2-G
Fonte:
ISI
Lingua:
ENG
Soggetto:
RU-CATALYZED OXIDATION; HYDROGEN-PEROXIDE; SELENOPHOSPHORYL COMPOUNDS; SELECTIVE OXIDATION; ORGANIC SULFIDES; IODOSYLBENZENE; SULFOXIDES; ALCOHOLS; ACETYLENES; ALDEHYDES;
Keywords:
oxidation; iodasobenzene; iodoxybenzene; organophosphates;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
44
Recensione:
Indirizzi per estratti:
Indirizzo: Lopusinski, A Polish Acad Sci, Ctr Mol & Macromol Studies, Sienkiewicza 112, PL-90363 Lodz, Poland Polish Acad Sci Sienkiewicza 112 Lodz Poland PL-90363 oland
Citazione:
G. Mielniczak e A. Lopusinski, "Iodosobenzene and iodoxybenzene as reagents for oxygen transfer in organophosphorus chemistry", SYNLETT, (4), 2001, pp. 505-508

Abstract

The application of iodosobenzene (1) and iodoxybenzene (2) for the oxidation reaction of phosphorous, phosphorothiono and phosphoroseleno compounds into the corresponding =P(O) analogs is demonstrated. Retention of configuration at the phosphorus atom and full stereoselectivity of these reactions in model diastereoisomeric cis- and trans-2-phenylamino-2-thiono-4-methyl-1 3,2-aphosphorinans (30) as well cis- and trans-2-phenylamino-2-seleno-4-methyl-1.3.2-diaxaphosphorinans (31) systems, are demonstrated.

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Documento generato il 03/07/20 alle ore 15:33:19