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Titolo:
Highly stereoselective Diels-Alder reactions achieved on some hexopyranosidic templates
Autore:
Nagatsuka, T; Yamaguchi, S; Totani, K; Takao, K; Tadano, K;
Indirizzi:
Keio Univ, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan Keio Univ Yokohama Kanagawa Japan 2238522 kohama, Kanagawa 2238522, Japan
Titolo Testata:
SYNLETT
fascicolo: 4, , anno: 2001,
pagine: 481 - 484
SICI:
0936-5214(200104):4<481:HSDRAO>2.0.ZU;2-#
Fonte:
ISI
Lingua:
ENG
Soggetto:
CHIRAL AUXILIARIES;
Keywords:
asymmetric synthesis; diastereoselectivity; Diels-Alder reaction; cyclopentadiene; norbornene derivatives;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
12
Recensione:
Indirizzi per estratti:
Indirizzo: Tadano, K Keio Univ, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan Keio Univ Yokohama Kanagawa Japan 2238522 nagawa 2238522, Japan
Citazione:
T. Nagatsuka et al., "Highly stereoselective Diels-Alder reactions achieved on some hexopyranosidic templates", SYNLETT, (4), 2001, pp. 481-484

Abstract

The Diels-Alder reactions of some carbohydrate derivatives, as chiral acrylic esters, with cyclopentadiene proceed highly diastereoselectively to provide the adducts carrying a norbornene carboxylate. By reductive removal ofthe carbohydrate templates from the adducts, both 2S and 2R-enriched 5-norbornene-2-methanol are obtained.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 05/12/20 alle ore 01:55:35