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Titolo:
Heterocyclopentadienyl complexes of group-3 metals
Autore:
Nief, F;
Indirizzi:
Ecole Polytech, CNRS UMR 7653, DCPH, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France Ecole Polytech Palaiseau France F-91128 dinat, F-91128 Palaiseau, France
Titolo Testata:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
fascicolo: 4, , anno: 2001,
pagine: 891 - 904
SICI:
1434-1948(200104):4<891:HCOGM>2.0.ZU;2-5
Fonte:
ISI
Lingua:
ENG
Soggetto:
RAY CRYSTAL-STRUCTURE; ORGANOMETALLIC COMPOUNDS; ARYLOXO-LANTHANOIDS; ORGANOAMIDO-LANTHANOIDS; MESO-OCTAETHYLPORPHYRINOGEN; MOLECULAR-STRUCTURE; PYRAZOLATE COMPLEXES; RUTHENIUM HYDRIDES; BOND-CLEAVAGE; SAMARIUM;
Keywords:
lanthanides; actinides; coordination modes; heteroelements; cyclopentadienes;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
73
Recensione:
Indirizzi per estratti:
Indirizzo: Nief, F Ecole Polytech, CNRS UMR 7653, DCPH, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France Ecole Polytech Palaiseau France F-91128 -91128 Palaiseau, France
Citazione:
F. Nief, "Heterocyclopentadienyl complexes of group-3 metals", EUR J INORG, (4), 2001, pp. 891-904

Abstract

Heterocyclopentadienyl complexes of group-3 metals (scandium, yttrium, lanthanum and the lanthanides, and uranium) are compounds in which one or more-CH units of a cyclopentadienyl-like ligand have been replaced by a heteroelement (nitrogen, phosphorus, arsenic, or antimony). These ligands can have very diverse substitution patterns, notably with bridged and cavitand-like structures. In addition to the classical eta (5)-coordination behaviour, the heterocyclopentadienyl ligand can adopt a very large array of coordination patterns. Some complexes have a very promising chemistry since they have been found to activate small molecules such as nitrogen and ethylene.

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Documento generato il 09/04/20 alle ore 07:12:11