Catalogo Articoli (Spogli Riviste)

OPAC HELP

Titolo:
Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate) interpenetration networks
Autore:
Liu, YH; Lin, CS; Chen, SY; Tsai, HL; Ueng, CH; Lu, KL;
Indirizzi:
Natl Taiwan Normal Univ, Dept Chem, Taipei 106, Taiwan Natl Taiwan Normal Univ Taipei Taiwan 106 Dept Chem, Taipei 106, Taiwan Natl Cheng Kung Univ, Dept Chem, Tainan 701, Taiwan Natl Cheng Kung Univ Tainan Taiwan 701 iv, Dept Chem, Tainan 701, Taiwan Acad Sinica, Inst Chem, Taipei 115, Taiwan Acad Sinica Taipei Taiwan 115Acad Sinica, Inst Chem, Taipei 115, Taiwan
Titolo Testata:
JOURNAL OF SOLID STATE CHEMISTRY
fascicolo: 1, volume: 157, anno: 2001,
pagine: 166 - 172
SICI:
0022-4596(20010215)157:1<166:HSACSO>2.0.ZU;2-X
Fonte:
ISI
Lingua:
ENG
Soggetto:
COORDINATION POLYMERS; MOLYBDENUM-OXIDE; BUILDING-BLOCKS; CHEMISTRY; DESIGN; FRAMEWORKS; SOLIDS; TRICYANOMETHANIDE; CARBOXYLATES; BINDING;
Keywords:
hydrothermal; nickel; cobalt; copper; metal-organic framework; interpenetration; coordination polymer; porous material; crystal structure;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
57
Recensione:
Indirizzi per estratti:
Indirizzo: Ueng, CH Natl Taiwan Normal Univ, Dept Chem, Taipei 106, Taiwan Natl Taiwan Normal Univ Taipei Taiwan 106 m, Taipei 106, Taiwan
Citazione:
Y.H. Liu et al., "Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate) interpenetration networks", J SOL ST CH, 157(1), 2001, pp. 166-172

Abstract

Three metal-organic polymeric networks, Ni(C8H6NO2)(2) (H2O)(2) (1), Co(C8H6NO2)(2) (2), and Cu(C8H6NO2)(2)(H2O)(2) (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cn(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing thesethree compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a = 13.735(3) Angstrom, b = 6.995(2) Angstrom, c = 16.723(3) Angstrom, V = 1606.7(6) Angstrom (3), Z = 4, final refinement (I > 2 sigma (I)): R1= 0.0296, wR2 = 0.0843. Crystal data for 2: monoclinic, space group Cc, a b = 21.2838(16) Angstrom, c = 8.5504(7) Angstrom, beta = 130.5210(10)degrees, V = 1600.8(2) Angstrom (3), Z = 4, final refinement (I > 2 sigma (I)): R1 = 0.0347, wR2 = 0.0879. Crystal data for 3: orthorhombic, space group Pbcn, a = 13.6844(13) Angstrom, b = 7.5053(8) Angstrom, c = 15.929(4) Angstrom, V = 1636.0(5) Angstrom (3), Z = 4, final refinement (I > 2 sigma (I)), R1= 0.0299, wR2 = 0.0787. (C) 2001 Academic Press.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 02/04/20 alle ore 12:48:29