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Titolo:
REGIOSELECTIVE SYNTHESIS OF THE HOMOCHIRAL LIGAND HYDRO-4,7-METHANOINDAZOL-2-YL-INDAZOL-1'-YLMETHANE
Autore:
LOPEZ MC; JAGEROVIC N; BALLESTEROS P;
Indirizzi:
UNIV CASTILLA LA MANCHA,EU POLITECN ALMADEN,DEPT QUIM INORGAN ORGAN &BIOQUIM ALMADEN SPAIN UNIV CASTILLA LA MANCHA,EU POLITECN ALMADEN,DEPT QUIM INORGAN ORGAN &BIOQUIM ALMADEN SPAIN CSIC,INST QUIM MED E-28006 MADRID SPAIN UNIV NACL EDUC DISTANCIA,FAC CIENCIAS,DEPT QUIM ORGAN & BIOL E-28040 MADRID SPAIN
Titolo Testata:
Tetrahedron : asymmetry
fascicolo: 10, volume: 5, anno: 1994,
pagine: 1887 - 1890
SICI:
0957-4166(1994)5:10<1887:RSOTHL>2.0.ZU;2-H
Fonte:
ISI
Lingua:
ENG
Soggetto:
CHIRAL HETEROCYCLIC LIGANDS; X-RAY STRUCTURE; COMPLEXES;
Tipo documento:
Note
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
15
Recensione:
Indirizzi per estratti:
Citazione:
M.C. Lopez et al., "REGIOSELECTIVE SYNTHESIS OF THE HOMOCHIRAL LIGAND HYDRO-4,7-METHANOINDAZOL-2-YL-INDAZOL-1'-YLMETHANE", Tetrahedron : asymmetry, 5(10), 1994, pp. 1887-1890

Abstract

The title new homochiral ligand has been prepared regioselectively byreaction of 8-trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazole with indazole in the presence of TosOH as catalyst using hexane or toluene as solvents. The structure has been unambiguously established by H-1 and C-13 NMR spectroscopy. Bis(indazol-1-yl)methane is obtained as secondary product as a consequence of an intermolecular dissociation-recombination process involved in the reaction.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 15/07/20 alle ore 08:14:38