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Titolo:
Ruthenium complex-catalyzed anti-Markovnikov hydration of terminal alkynes
Autore:
Suzuki, T; Tokunaga, M; Wakatsuki, Y;
Indirizzi:
RIKEN, Inst Phys & Chem Res, Wako, Saitama 3510198, Japan RIKEN Wako Saitama Japan 3510198 & Chem Res, Wako, Saitama 3510198, Japan Japan Sci & Technol Corp, PRESTO, Wako, Saitama 3510198, Japan Japan Sci &Technol Corp Wako Saitama Japan 3510198 aitama 3510198, Japan
Titolo Testata:
ORGANIC LETTERS
fascicolo: 5, volume: 3, anno: 2001,
pagine: 735 - 737
SICI:
1523-7060(20010308)3:5<735:RCAHOT>2.0.ZU;2-E
Fonte:
ISI
Lingua:
ENG
Soggetto:
WATER;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
17
Recensione:
Indirizzi per estratti:
Indirizzo: Wakatsuki, Y RIKEN, Inst Phys & Chem Res, Wako, Saitama 3510198, Japan RIKEN Wako Saitama Japan 3510198 ako, Saitama 3510198, Japan
Citazione:
T. Suzuki et al., "Ruthenium complex-catalyzed anti-Markovnikov hydration of terminal alkynes", ORG LETT, 3(5), 2001, pp. 735-737

Abstract

[GRAPHICS]Highly regioselective, efficient, acid substituent-tolerant anti-Markovnikov hydration of terminal alkynes occurs to give n-aldehyde by use of a catalytic amount of easily available cyclopentadienylruthenium complexes bearing appropriate bidentate or monodentate phosphine ligands, Typically, RuCpCl(dppm) (1 mol %) catalyzes the addition of water to 1-hexyne at 100 degreesC to give hexanal in 95% yield: 2-hexanone is not detected at all.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 22/01/20 alle ore 22:16:32