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Titolo:
Synthesis and coordination chemistry of PEt(C6H4-4-C6F13)(2). Crystal structure of cis-[PtCl2{Pet(C6H4-4C(6)F(13))(2)}(2)]
Autore:
Fawcett, J; Hope, EG; Russell, DR; Stuart, AM; Wood, DRW;
Indirizzi:
Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England Univ Leicester Leicester Leics England LE1 7RH er LE1 7RH, Leics, England
Titolo Testata:
POLYHEDRON
fascicolo: 3-4, volume: 20, anno: 2001,
pagine: 321 - 326
SICI:
0277-5387(20010215)20:3-4<321:SACCOP>2.0.ZU;2-Q
Fonte:
ISI
Lingua:
ENG
Soggetto:
FLUOROUS BIPHASE; COMPLEXES; PHOSPHINES; LIGANDS;
Keywords:
fluorous biphase; phosphine; platinum group metals; single crystal X-ray study;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
22
Recensione:
Indirizzi per estratti:
Indirizzo: Hope, EG Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England UnivLeicester Leicester Leics England LE1 7RH H, Leics, England
Citazione:
J. Fawcett et al., "Synthesis and coordination chemistry of PEt(C6H4-4-C6F13)(2). Crystal structure of cis-[PtCl2{Pet(C6H4-4C(6)F(13))(2)}(2)]", POLYHEDRON, 20(3-4), 2001, pp. 321-326

Abstract

The synthesis and coordination chemistry of the PEt(C6H4-4-C6F13)(2) ligand has been investigated including the single crystal X-ray structural characterisation of cis-[PtCl2{PEt(C6H4-C6F13)(2)}(2)]. The spectroscopic data for [RhCl2(eta (5)-C5Me5)L], trans[MCl(CO)L-2] (M = Rh, Ir) and cis-[PtCl2L2] {L = PEt(C6H4-4-C6F13)(2)} indicate that the ethyl group is unable to meliorate against the electron withdrawing effects of the perfluoroalkyl groups. The crystal structure illustrates that the perfluoroalkyl groups have little influence on the platinum coordination environment but that the solid state packing is dominated by short F . . .F interactions. (C) 2001 Elsevier Science B.V. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 05/04/20 alle ore 19:30:15