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Titolo:
The criterion of critical runaway and stable temperatures in cumene hydroperoxide reaction
Autore:
Luo, KM; Chang, JG; Lin, SH; Chang, CT; Yeh, TF; Hu, KH; Kao, CS;
Indirizzi:
Chung Cheng Inst Technol, Dept Appl Chem, Tashi 33509, Taoyuan, Taiwan Chung Cheng Inst Technol Tashi Taoyuan Taiwan 33509 3509, Taoyuan, Taiwan Ctr Ind Safety & Hlth Technol, Ind Technol Res Inst, Hsinchu, Taiwan Ctr Ind Safety & Hlth Technol Hsinchu Taiwan Res Inst, Hsinchu, Taiwan
Titolo Testata:
JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES
fascicolo: 3, volume: 14, anno: 2001,
pagine: 229 - 239
SICI:
0950-4230(200105)14:3<229:TCOCRA>2.0.ZU;2-3
Fonte:
ISI
Lingua:
ENG
Soggetto:
STABILITY;
Keywords:
cumene hydroperoxide; critical runaway temperature; stable reaction criteria;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Engineering, Computing & Technology
Citazioni:
9
Recensione:
Indirizzi per estratti:
Indirizzo: Luo, KM Chung Cheng Inst Technol, Dept Appl Chem, Tashi 33509, Taoyuan, Taiwan Chung Cheng Inst Technol Tashi Taoyuan Taiwan 33509 oyuan, Taiwan
Citazione:
K.M. Luo et al., "The criterion of critical runaway and stable temperatures in cumene hydroperoxide reaction", J LOSS PREV, 14(3), 2001, pp. 229-239

Abstract

Cumene hydroperoxide (CHP) has been used as an initiator in polymerizationand catalytic cleavage in the production process of phenol and acetone. Itis usually produced by the cumene oxidation reaction. In its manufacturingprocesses, many explosion and fire incidents are caused by this material owing to its thermal instability or incompatibility in its oxidation reaction or concentrated processes. Thus, the reactive hazard on this material hasto be clearly identified and its critical runaway temperature and unstablereaction criterion has to be determined. In this investigation, the critical runaway temperature and stable reaction criterion with the initial concentrations of 15 wt% and 20 wt% CHP in its reaction processes were evaluatedfrom their reaction kinetic parameters. The results are important and useful in the production, transportation and storage processes of CHP. (C) 2001Elsevier Science Ltd, All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 11/07/20 alle ore 07:33:41