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Titolo:
Synthesis and solid-state structure of (Li4Am3)(+)center dot{Li[(mu-Me)(2)Al(Me)tBu](2)}(-) {Am = [PhNC(Ph)NPh](-)}: A polymeric species incorporating a lithium-nitrogen cluster cation
Autore:
Davies, RP; Linton, DJ; Schooler, P; Snaith, R; Wheatley, AEH;
Indirizzi:
Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England Univ Cambridge Cambridge England CB2 1EW hem, Cambridge CB2 1EW, England Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England Univ London Imperial Coll Sci Technol & Med London England SW7 2AY gland
Titolo Testata:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
fascicolo: 3, , anno: 2001,
pagine: 619 - 622
SICI:
1434-1948(200103):3<619:SASSO(>2.0.ZU;2-1
Fonte:
ISI
Lingua:
ENG
Soggetto:
GALLIUM AMIDINATE COMPLEXES; CRYSTAL-STRUCTURE; MAIN-GROUP; COORDINATION CHEMISTRY; POTASSIUM; ALUMINUM; LIGANDS; OXYGEN; ION; LI;
Keywords:
aluminum; cluster compounds; cations; lithium;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
53
Recensione:
Indirizzi per estratti:
Indirizzo: Wheatley, AEH Univ Cambridge, Dept Chem, Lensfield Rd, Cambridge CB2 1EW, England Univ Cambridge Lensfield Rd Cambridge England CB2 1EW gland
Citazione:
R.P. Davies et al., "Synthesis and solid-state structure of (Li4Am3)(+)center dot{Li[(mu-Me)(2)Al(Me)tBu](2)}(-) {Am = [PhNC(Ph)NPh](-)}: A polymeric species incorporating a lithium-nitrogen cluster cation", EUR J INORG, (3), 2001, pp. 619-622

Abstract

The sequential reaction of PhN(H)C(Ph)NPh (AmH) with ALMe(3) and tBuLi leads to the isolation of both the cluster (Li4Am3)(+). {Li[(mu -Me)(2)Al(Me)tBu](2)}(-) (5) and the aluminium tris(amidinate) AIAm(3) (6). In the solid state, 5 has a polymeric structure based on tetranuclear Lh-cluster cationsand Lithium bis(aluminate) anions which associate by the formation of weakLi . . . MeAl bonds.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 20/09/20 alle ore 01:07:25