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Titolo:
Further investigations into the isomerism of Cu(II) complexes of diphenylsulfimide: the preparation and X-ray crystal structure of {[Cu(Ph2SNH)(4)][CuBr2(Ph2SNH)(2)]Br-2}, the first example of a {[CuL4][CuX2L2]X-2} structure
Autore:
Kelly, PF; Slawin, AMZ; Waring, KW; Wilson, S;
Indirizzi:
Loughborough Univ Technol, Dept Chem, Loughborough LE11 3TU, Leics, England Loughborough Univ Technol Loughborough Leics England LE11 3TU cs, England Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland Univ St Andrews St Andrews Fife Scotland KY16 9ST Y16 9ST, Fife, Scotland
Titolo Testata:
INORGANICA CHIMICA ACTA
fascicolo: 1-2, volume: 312, anno: 2001,
pagine: 201 - 204
SICI:
0020-1693(20010129)312:1-2<201:FIITIO>2.0.ZU;2-M
Fonte:
ISI
Lingua:
ENG
Keywords:
isomerism; copper(II) complexes; crystal structures; sulfimides;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
6
Recensione:
Indirizzi per estratti:
Indirizzo: Kelly, PF Loughborough Univ Technol, Dept Chem, Loughborough LE11 3TU, Leics, England Loughborough Univ Technol Loughborough Leics England LE11 3TU d
Citazione:
P.F. Kelly et al., "Further investigations into the isomerism of Cu(II) complexes of diphenylsulfimide: the preparation and X-ray crystal structure of {[Cu(Ph2SNH)(4)][CuBr2(Ph2SNH)(2)]Br-2}, the first example of a {[CuL4][CuX2L2]X-2} structure", INORG CHIM, 312(1-2), 2001, pp. 201-204

Abstract

Green crystalline [Cu(Ph2SNH)(4)][CuBr2(Ph2SNH)(2)]Br-2 (2) forms when theproduct of the reaction of CuBr2 with Ph2SNH (1) (molar ratio 1:3) in MeCNis extracted into CH2Cl2-60/80 petroleum ether and the solvents allowed toevaporate slowly. The product is notable for two reasons: not only does itcontain the CuBr2(Ph2SNH)(2) unit in the hitherto unseen planar isomer (the free material forming only the pseudo-tetrahedral isomer), but, more significantly, it is also the first example of a structurally characterised [CuL4][CuX2L2]X-2 system. (C) 2001 Elsevier Science B.V. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 04/12/20 alle ore 19:47:29