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Titolo:
The antioxidant role of vitamin E in polymers. IV. Reaction products of DL-alpha-tocopherol with lead dioxide and with polyolefins
Autore:
Al-Malaika, S; Issenhuth, S;
Indirizzi:
Aston Univ, Sch Engn & Appl Sci, Polymer Proc & Performance Res Unit, Birmingham B4 7ET, W Midlands, England Aston Univ Birmingham W Midlands England B4 7ET 7ET, W Midlands, England
Titolo Testata:
POLYMER
fascicolo: 7, volume: 42, anno: 2001,
pagine: 2915 - 2939
SICI:
0032-3861(200103)42:7<2915:TAROVE>2.0.ZU;2-H
Fonte:
ISI
Lingua:
ENG
Soggetto:
PERFORMANCE LIQUID-CHROMATOGRAPHY; TRANSFORMATION PRODUCTS; OXIDATION-PRODUCTS; MODEL-COMPOUND; SEPARATION; RADICALS;
Keywords:
alpha-tocopherol; vitamin E; polyolefins;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
19
Recensione:
Indirizzi per estratti:
Indirizzo: Al-Malaika, S Aston Univ, Sch Engn & Appl Sci, Polymer Proc & Performance Res Unit, Aston Triangle, Birmingham B4 7ET, W Midlands, England Aston UnivAston Triangle Birmingham W Midlands England B4 7ET
Citazione:
S. Al-Malaika e S. Issenhuth, "The antioxidant role of vitamin E in polymers. IV. Reaction products of DL-alpha-tocopherol with lead dioxide and with polyolefins", POLYMER, 42(7), 2001, pp. 2915-2939

Abstract

The reaction products of lead dioxide oxidation of the synthetic biological antioxidant DL-alpha -tocopherol in hexane were investigated at differentmolar ratios. products were separated by normal phase high-performance liquid chromatography (HPLC) and isolated using semipreparative HPLC. Four isomeric trimers and three isomeric spirodimers were obtained as the major reaction products in the presence of 10 and 40 molar excess of the oxidant PbO2, respectively, whereas the aldehyde, 5-formyl-gamma -tocopherol. was obtained as a minor product at 40 molar excess of PbO2. Dihydroxydimers were formed as minor products at the stoichiometric ratio of tocopherol to PbO2, and were also obtained as major products from a reaction of the spirodimer with LiAlH4; three isomeric dihydroxydimers were obtained from both reactions. The structures of the different products were characterised by FTIR, UV-vis, H-1-NMR, C-13-NMR, EI-MS and FAB-MS, and based on these results possible structures of the isomeric forms of the products are suggested. Characterisation of products obtained from the oxidation of DL-alpha -tocopherol in solution reported here has enabled the identification of a large number of oxidation products, including isomeric forms, detected and isolated from high-temperature melt reactions of the antioxidant DL-alpha -tocopherol in polyethylene and polypropylene. (C) 2001 Elsevier Science Ltd. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 14/07/20 alle ore 11:40:19