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Titolo:
TEMPERATURE-DEPENDENCE OF THE RATE-CONSTANT FOR THE CL-+CH3BR REACTION DOWN TO 23 K
Autore:
LEGARREC JL; ROWE BR; QUEFFELEC JL; MITCHELL JBA; CLARY DC;
Indirizzi:
UNIV RENNES 1,UMR 6627 CNRS,PALMS,CAMPUS BEAULIEU F-35042 RENNES FRANCE UNIV LONDON UNIV COLL,DEPT CHEM LONDON WC1H 0AJ ENGLAND
Titolo Testata:
The Journal of chemical physics
fascicolo: 3, volume: 107, anno: 1997,
pagine: 1021 - 1024
SICI:
0021-9606(1997)107:3<1021:TOTRFT>2.0.ZU;2-A
Fonte:
ISI
Lingua:
ENG
Soggetto:
ELECTRON-ATTACHMENT REACTIONS; GAS-PHASE; RATE COEFFICIENTS; FALP TECHNIQUE; SN2 REACTIONS; CH3BR; KINETICS; DYNAMICS; 200-K; CF3BR;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
21
Recensione:
Indirizzi per estratti:
Citazione:
J.L. Legarrec et al., "TEMPERATURE-DEPENDENCE OF THE RATE-CONSTANT FOR THE CL-+CH3BR REACTION DOWN TO 23 K", The Journal of chemical physics, 107(3), 1997, pp. 1021-1024

Abstract

Rate constants measured for the Cl-+CH3Br-->CH3Cl+Br- reaction increase by over two orders of magnitude when the temperature is reduced from 300 to 23 K. Calculations done with the rotating bond approximation provide a simple explanation of this unusually strong negative temperature dependence of the rate constant. (C) 1997 American Institute of Physics.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 30/11/20 alle ore 18:02:42