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Titolo:
Enantioselective syntheses of authentic sclerophytin A, sclerophytin B, and cladiell-11-ene-3,6,7-triol
Autore:
Gallou, F; MacMillan, DWC; Overman, LE; Paquette, LA; Pennington, LD; Yang, J;
Indirizzi:
Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA Univ Calif Irvine Irvine CA USA 92697 ne, Dept Chem, Irvine, CA 92697 USA Ohio State Univ, Dept Chem, Columbus, OH 43210 USA Ohio State Univ Columbus OH USA 43210 , Dept Chem, Columbus, OH 43210 USA
Titolo Testata:
ORGANIC LETTERS
fascicolo: 1, volume: 3, anno: 2001,
pagine: 135 - 137
SICI:
1523-7060(20010111)3:1<135:ESOASA>2.0.ZU;2-I
Fonte:
ISI
Lingua:
ENG
Soggetto:
SOFT CORAL; ALCOHOLS; DITERPENES; CAPITALIS; CHEMISTRY; 1,2-DIOLS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
21
Recensione:
Indirizzi per estratti:
Indirizzo: Overman, LE Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA Univ Calif Irvine Irvine CA USA 92697 m, Irvine, CA 92697 USA
Citazione:
F. Gallou et al., "Enantioselective syntheses of authentic sclerophytin A, sclerophytin B, and cladiell-11-ene-3,6,7-triol", ORG LETT, 3(1), 2001, pp. 135-137

Abstract

[GRAPHICS]Two distinctively different total syntheses of natural sclerophytin A in its revised structural formulation are reported. The first proceeds from (S)-carvone via a cladiellene triol and involves photoisomerization of the double bond, The second route makes use of (5S)-5-(d-menthyloxy)-2(5H)-furanone, which is subjected to cycloaddition, Claisen ring expansion, and regiocontrolled dihydroxylation tactics.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 25/11/20 alle ore 01:35:44