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Titolo:
Corrections to moving chemical reaction boundary equation for weak reactive electrolytes under the existence of background electrolyte KC1 in large concentrations
Autore:
Cao, CX; Zhou, SL; He, YZ; Qian, YT; Yang, L; Qu, QS; Gan, WE; Dong, L; Zhao, YQ; Chen, WK;
Indirizzi:
Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China Univ Sci & Technol China Hefei Peoples R China 230026 6, Peoples R China Wannan Med Coll, Inst Allergy React, Wuhu 241001, Peoples R China Wannan Med Coll Wuhu Peoples R China 241001 Wuhu 241001, Peoples R China
Titolo Testata:
JOURNAL OF CHROMATOGRAPHY A
fascicolo: 1-2, volume: 907, anno: 2001,
pagine: 347 - 352
Fonte:
ISI
Lingua:
ENG
Soggetto:
CAPILLARY ZONE ELECTROPHORESIS; MOBILITIES; AMPHOLYTES; SIMULATION; OH;
Keywords:
moving chemical reaction boundary; background electrolyte composition; isoelectric focusing; ammonia; acetic acid;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Life Sciences
Physical, Chemical & Earth Sciences
Citazioni:
29
Recensione:
Indirizzi per estratti:
Indirizzo: Cao, CX Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R ChinaUniv Sci & Technol China Hefei Peoples R China 230026 es R China
Citazione:
C.X. Cao et al., "Corrections to moving chemical reaction boundary equation for weak reactive electrolytes under the existence of background electrolyte KC1 in large concentrations", J CHROMAT A, 907(1-2), 2001, pp. 347-352

Abstract

In this report, the moving chemical reaction boundary (MCRB) was formed bythe weak reaction electrolytes of NH3.H2O and CH3COOH under the existence of background electrolyte KCl in large concentrations, the experiments werecompared with the predictions by the moving chemical reaction boundary equation (MCRBE) for weak reactive electrolytes.. It was found that the experimental results are far from the predictions with the MCRBE. So the MCRBEs must be corrected under the given experimental conditions. The corrected MCRBEs are given for the MCRB formed with weak reactive electrolytes coupled with KCl at high concentrations. (C) 2001 Elsevier Science B.V. All rights reserved.

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Documento generato il 20/09/20 alle ore 09:39:02