Catalogo Articoli (Spogli Riviste)

OPAC HELP

Titolo:
Further investigation into the platinum-activated addition of diphenylsulfimide to acetonitrile; the X-ray crystal structure of [PPh4][PtCl2(Ph2SNC(Me)NH)](2)Cl
Autore:
Kelly, PF; Slawin, AMZ;
Indirizzi:
Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England Univ Loughborough Loughborough Leics England LE11 3TU 3TU, Leics, England Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland Univ St Andrews St Andrews Fife Scotland KY16 9ST Y16 9ST, Fife, Scotland
Titolo Testata:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
fascicolo: 1, , anno: 2001,
pagine: 263 - 265
SICI:
1434-1948(200101):1<263:FIITPA>2.0.ZU;2-3
Fonte:
ISI
Lingua:
ENG
Soggetto:
COMPLEXES;
Keywords:
sulfur; nitrogen; platinum; sulfimides; nitriles;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
7
Recensione:
Indirizzi per estratti:
Indirizzo: Kelly, PF Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England Univ Loughborough Loughborough Leics England LE11 3TU , England
Citazione:
P.F. Kelly e A.M.Z. Slawin, "Further investigation into the platinum-activated addition of diphenylsulfimide to acetonitrile; the X-ray crystal structure of [PPh4][PtCl2(Ph2SNC(Me)NH)](2)Cl", EUR J INORG, (1), 2001, pp. 263-265

Abstract

Reaction of Ph2SNH (1) with [PtCl2(MeCN)(2)] (1:1 ratio) in MeCN at 50 degreesC results in the formation of [PtCl2{Ph2SNC (Me)NH}] (3); without heating [Pt(Ph2SNH)-(Ph2SNC (Me)NH}Cl]Cl (2) is the primary product. Attempts togrow X-ray quality crystals of 3 have not succeeded; it does, however, form a crystalline 2:1 adduct with [PPh4]Cl (3a), the structure of which confirms the presence of the bidentate Ph2SNC(Me)NH ligand hydrogen-bonded to the chloride anion. Reaction of 3 with three equivalents of 1 and two of Tl[PF6] results in the formation of [Pt(Ph2SNH)(2){Ph2SNC(Me)NH}(2)][PF6](2) (4), the first example of a complex containing the [Ph2SNC(Me)N(H)] unit acting as a monodentate ligand, bound through the nitrogen atom.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 02/12/20 alle ore 03:20:59