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Titolo:
Grignard reagent mediated reaction of Cp2Zr(II)-ethylene complex with imines
Autore:
Takahashi, T; Liu, YH; Xi, CJ; Huo, SQ;
Indirizzi:
Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0600811, Japan Hokkaido Univ Sapporo Hokkaido Japan 0600811 oro, Hokkaido 0600811, Japan Hokkaido Univ, Grad Sch Pharmaceut Sci, Sapporo, Hokkaido 0600811, Japan Hokkaido Univ Sapporo Hokkaido Japan 0600811 oro, Hokkaido 0600811, Japan Sci & Technol Corp, CREST, Sapporo, Hokkaido 0600811, Japan Sci & Technol Corp Sapporo Hokkaido Japan 0600811 Hokkaido 0600811, Japan
Titolo Testata:
CHEMICAL COMMUNICATIONS
fascicolo: 01, , anno: 2001,
pagine: 31 - 32
SICI:
1359-7345(2001):01<31:GRMROC>2.0.ZU;2-Z
Fonte:
ISI
Lingua:
ENG
Soggetto:
ZIRCONIUM; ZIRCONACYCLOPENTANE; DERIVATIVES; MAGNESIUM;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
14
Recensione:
Indirizzi per estratti:
Indirizzo: Takahashi, T Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0600811, Japan Hokkaido Univ Sapporo Hokkaido Japan 0600811 0600811, Japan
Citazione:
T. Takahashi et al., "Grignard reagent mediated reaction of Cp2Zr(II)-ethylene complex with imines", CHEM COMMUN, (01), 2001, pp. 31-32

Abstract

Imines which do not react with Grignard reagents reacted with EtMgBr in the presence of a catalytic amount of Cp2ZrCl2 to give ethylated products in excellent yields; the stoichiometric reaction of the imines and the zirconocene-ethylene complex did not give the ethylated product, whereas addition of MeMgBr or BuMgCl to the mixture afforded the ethylated product after hydrolysis.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 03/04/20 alle ore 07:06:36