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Titolo:
Spectral patterns of chaotic acetylene
Autore:
Rose, JP; Kellman, ME;
Indirizzi:
Univ Oregon, Dept Chem, Eugene, OR 97403 USA Univ Oregon Eugene OR USA 97403 v Oregon, Dept Chem, Eugene, OR 97403 USA
Titolo Testata:
JOURNAL OF PHYSICAL CHEMISTRY A
fascicolo: 45, volume: 104, anno: 2000,
pagine: 10471 - 10481
SICI:
1089-5639(20001116)104:45<10471:SPOCA>2.0.ZU;2-G
Fonte:
ISI
Lingua:
ENG
Soggetto:
DISPERSED FLUORESCENCE-SPECTRA; INTRAMOLECULAR VIBRATIONAL REDISTRIBUTION; FERMI RESONANCE-SPECTRA; BIFURCATION-ANALYSIS; BENDING DYNAMICS; INTERNAL ENERGY; STATE; (C2H2)-C-12; TRANSITION; CONSTANTS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
40
Recensione:
Indirizzi per estratti:
Indirizzo: Kellman, ME Univ Oregon, Dept Chem, Eugene, OR 97403 USA Univ Oregon Eugene OR USA 97403 pt Chem, Eugene, OR 97403 USA
Citazione:
J.P. Rose e M.E. Kellman, "Spectral patterns of chaotic acetylene", J PHYS CH A, 104(45), 2000, pp. 10471-10481

Abstract

A diabatic correlation diagram procedure, first applied (Rose, J. P.; Kellman, M. E., J. Chem. Phys. 1996, 105, 7348) to H2O, is used to classify energy and intensity patterns in the highly excited bending spectrum of C2H2, modeled by an effective spectroscopic fitting Hamiltonian. Analysis with polyad phase spheres accounts for the observed patterns in terms of classicalphase space structure and bifurcations of the low-energy normal modes.

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Documento generato il 02/07/20 alle ore 19:03:52