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Titolo:
Consequences of affinity in heterogeneous catalytic reactions: Highly chemoselective hydrogenolysis of iodoarenes
Autore:
Ambroise, Y; Mioskowski, C; Djega-Mariadassou, G; Rousseau, B;
Indirizzi:
CEA Saclay, Serv Mol Marquees, F-91191 Gif Sur Yvette, France CEA Saclay Gif Sur Yvette France F-91191 F-91191 Gif Sur Yvette, France Univ Paris 06, Lab React Surface, F-75252 Paris, France Univ Paris 06 Paris France F-75252 React Surface, F-75252 Paris, France
Titolo Testata:
JOURNAL OF ORGANIC CHEMISTRY
fascicolo: 21, volume: 65, anno: 2000,
pagine: 7183 - 7186
SICI:
0022-3263(20001020)65:21<7183:COAIHC>2.0.ZU;2-#
Fonte:
ISI
Lingua:
ENG
Soggetto:
HIGH SPECIFIC RADIOACTIVITY; PHOSPHOLIPIDIC PROBE; MEMBRANE; ANALOG; AFLATOXIN-B2; SELECTIVITY; RADIOLIGAND; RECEPTORS; PROTEINS; REAGENT;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Life Sciences
Physical, Chemical & Earth Sciences
Citazioni:
44
Recensione:
Indirizzi per estratti:
Indirizzo: Rousseau, B CEA Saclay, Serv Mol Marquees, F-91191 Gif Sur Yvette, France CEA Saclay Gif Sur Yvette France F-91191 Sur Yvette, France
Citazione:
Y. Ambroise et al., "Consequences of affinity in heterogeneous catalytic reactions: Highly chemoselective hydrogenolysis of iodoarenes", J ORG CHEM, 65(21), 2000, pp. 7183-7186

Abstract

The catalytic hydrodeibdination reaction using molecular hydrogen and Pd/Chas been revisited. It is shown, for the first time, that the chemoselectivity of this reaction is controlled by the high affinity of the iodinated compound for the catalyst. This reaction is compatible with most easily reducible functional groups (nitro, aldehyde, olefin, etc:). Using this reaction, the first general method for tritium labeling of 3-(triflubromethyl)-3-phenyldiazirine is described.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 05/07/20 alle ore 07:26:44