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Titolo:
The preparation of the first examples of sulfimide complexes of platinum; the X-ray crystal structure of [Pt(Ph2SNH)(4)]Cl-2
Autore:
Kelly, PF; Macklin, AC; Slawin, AMZ; Waring, KW;
Indirizzi:
Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England Univ Loughborough Loughborough Leics England LE11 3TU 3TU, Leics, England
Titolo Testata:
POLYHEDRON
fascicolo: 18-19, volume: 19, anno: 2000,
pagine: 2077 - 2081
SICI:
0277-5387(20000930)19:18-19<2077:TPOTFE>2.0.ZU;2-3
Fonte:
ISI
Lingua:
ENG
Soggetto:
PD;
Keywords:
complexes; platinum; sulfimides; hydrogen bonding;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
13
Recensione:
Indirizzi per estratti:
Indirizzo: Kelly, PF Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England Univ Loughborough Loughborough Leics England LE11 3TU , England
Citazione:
P.F. Kelly et al., "The preparation of the first examples of sulfimide complexes of platinum; the X-ray crystal structure of [Pt(Ph2SNH)(4)]Cl-2", POLYHEDRON, 19(18-19), 2000, pp. 2077-2081

Abstract

The reactivity of S,S-diphenylsulfimide, Ph2SNH, (1) towards platinum complexes has been investigated. Solutions of 1 and [PtCl2(PMe2Ph)(2)] show an equilibrium between the starting materials and cis-[PtCl(Ph2SNH)(PMe2Ph)(2)]Cl; addition of [NH4][BF4] generates pure cis-[PtCl(Ph2SNH)(PMe2Ph)(2)][BF4] (2). Four equivalents of 1 react with [PPh4](2)[PtCl4] over a period of days to give crystalline [Pt(Ph2SNH)(4)]Cl-2 (3); the crystal structure of 3 confirms the expected square planar geometry with significant H-bonding interactions between the cation and the chlorides. (C) 2000 Elsevier ScienceLtd. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 24/11/20 alle ore 13:41:51