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Titolo:
The vibrational energy pattern in acetylene (VI): Inter- and intrapolyad structures
Autore:
Zhilinskii, BI; El Idrissi, MI; Herman, M;
Indirizzi:
Free Univ Brussels, Lab Chim Phys Mol, B-1050 Brussels, Belgium Free Univ Brussels Brussels Belgium B-1050 Mol, B-1050 Brussels, Belgium Univ Littoral, MREID, F-59140 Dunkerque 1, France Univ Littoral Dunkerque France 1 ral, MREID, F-59140 Dunkerque 1, France
Titolo Testata:
JOURNAL OF CHEMICAL PHYSICS
fascicolo: 18, volume: 113, anno: 2000,
pagine: 7885 - 7890
SICI:
0021-9606(20001108)113:18<7885:TVEPIA>2.0.ZU;2-G
Fonte:
ISI
Lingua:
ENG
Soggetto:
DISPERSED FLUORESCENCE-SPECTRA; (C2H2)-C-12; DYNAMICS; SPECTROSCOPY; MOLECULES; STATE; MODES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
22
Recensione:
Indirizzi per estratti:
Indirizzo: Herman, M Free Univ Brussels, Lab Chim Phys Mol, CP 160-09,Ave Roosevelt 50, B-1050 Brussels, Belgium Free Univ Brussels CP 160-09,Ave Roosevelt 50 Brussels Belgium B-1050
Citazione:
B.I. Zhilinskii et al., "The vibrational energy pattern in acetylene (VI): Inter- and intrapolyad structures", J CHEM PHYS, 113(18), 2000, pp. 7885-7890

Abstract

Intra- and interpolyad structures are investigated in the vibrational energy pattern of acetylene, using the spectroscopic Hamiltonian presented in previous papers in this series [see El Idrissi , J. Chem. Phys. 110, 2074 (1999)]. The existence of two constants of the motion is shown to generate very regular patterns in the manifold of vibrational energy levels. Distinct regular and oscillatory contributions are evidenced in the number of vibrational levels in the main polyads, which are fully reproduced using the generating function presented in Sadovskii and Zhilinskii [J. Chem. Phys. 103, 10520 (1995)]. Further developments of this approach are outlined. (C) 2000American Institute of Physics. [S0021-9606(00)01442-2].

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Documento generato il 22/09/20 alle ore 20:43:14