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Titolo:
Reaction of silazirconacyclopentene formed from zirconium-silene complex and alkyne with isocyanide
Autore:
Kuroda, S; Sato, Y; Mori, M;
Indirizzi:
Hokkaido Univ, Grad Sch Pharmaceut Sci, Sapporo, Hokkaido 0600812, Japan Hokkaido Univ Sapporo Hokkaido Japan 0600812 oro, Hokkaido 0600812, Japan
Titolo Testata:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
fascicolo: 1-2, volume: 611, anno: 2000,
pagine: 304 - 307
SICI:
0022-328X(20001006)611:1-2<304:ROSFFZ>2.0.ZU;2-Q
Fonte:
ISI
Lingua:
ENG
Soggetto:
ETA-2-SILANIMINE COMPLEXES; CARBON-MONOXIDE; DERIVATIVES; SILICON; AZAZIRCONACYCLOPENTENE; TRIMETHYLSILYL; ZIRCONOCENE; INSERTION; METALS; BONDS;
Keywords:
silene; zirconium-silene complex; iminosilazirconacyclohexene; isocyanide; silazirconacyclopentene;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
21
Recensione:
Indirizzi per estratti:
Indirizzo: Mori, M Hokkaido Univ, Grad Sch Pharmaceut Sci, Sapporo, Hokkaido 0600812,Japan Hokkaido Univ Sapporo Hokkaido Japan 0600812 kaido 0600812, Japan
Citazione:
S. Kuroda et al., "Reaction of silazirconacyclopentene formed from zirconium-silene complex and alkyne with isocyanide", J ORGMET CH, 611(1-2), 2000, pp. 304-307

Abstract

The reaction of silazirconacyclopentene (3), which was formed from zirconium-silene complex 1 and diarylacetylene (5), with tert-butyl isocyanide afforded iminosilazirconacyclohexene (7). Treatment of iminosilazirconacyclohexene (7) with HCl-Et2O gave the imino-zirconium complex 6, whose structure was confirmed by X-ray crystallography. The reaction was monitored by H-1-NMR spectroscopy. (C) 2000 Elsevier Science S.A. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 27/11/20 alle ore 01:10:29