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Titolo:
Applications of homoallylic alcohols derived from (-)-sparteine-mediated asymmetric homoaldolization: Entry to 5-to 8-membered unsaturated oxacycles through metathesis reaction
Autore:
Prasad, KRK; Hoppe, D;
Indirizzi:
Univ Munster, Inst Organ Chem, D-48149 Munster, Germany Univ Munster Munster Germany D-48149 rgan Chem, D-48149 Munster, Germany
Titolo Testata:
SYNLETT
fascicolo: 7, , anno: 2000,
pagine: 1067 - 1069
SICI:
0936-5214(200007):7<1067:AOHADF>2.0.ZU;2-P
Fonte:
ISI
Lingua:
ENG
Soggetto:
RING-CLOSING-METATHESIS; OLEFIN METATHESIS; ENANTIOSELECTIVE CONSTRUCTION; OXYGEN HETEROCYCLES; ORGANIC-SYNTHESIS; SUB-UNITS; ETHERS; ROUTE; STRATEGY; ACID;
Keywords:
(-)-sparteine; homoaldolization; asymmetric synthesis; oxacycloalkenes; ring-closing metathesis;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
36
Recensione:
Indirizzi per estratti:
Indirizzo: Hoppe, D Univ Munster, Inst Organ Chem, Corrensstr 40, D-48149 Munster, Germany Univ Munster Corrensstr 40 Munster Germany D-48149 ster, Germany
Citazione:
K.R.K. Prasad e D. Hoppe, "Applications of homoallylic alcohols derived from (-)-sparteine-mediated asymmetric homoaldolization: Entry to 5-to 8-membered unsaturated oxacycles through metathesis reaction", SYNLETT, (7), 2000, pp. 1067-1069

Abstract

A series of enantioenriched 4-hydroxy-1-alkenyl carbamates was prepared by(-)-sparteine-mediated homoaldolization. These were transformed into unsaturated oxacycles, involving simple synthetic transformations, with ring-closing metathesis (RCM) as the key step.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 26/01/20 alle ore 01:37:19