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Titolo:
Synthesis and reactivity of arenes coordinated to cyclopentadienyliron cations
Autore:
Abd-El-Aziz, AS; Bernardin, S;
Indirizzi:
Univ Winnipeg, Dept Chem, Winnipeg, MB R3B 2E9, Canada Univ Winnipeg Winnipeg MB Canada R3B 2E9 em, Winnipeg, MB R3B 2E9, Canada
Titolo Testata:
COORDINATION CHEMISTRY REVIEWS
, volume: 203, anno: 2000,
pagine: 219 - 267
SICI:
0010-8545(200006)203:<219:SAROAC>2.0.ZU;2-N
Fonte:
ISI
Lingua:
ENG
Soggetto:
LIGAND-EXCHANGE REACTIONS; NUCLEOPHILIC-SUBSTITUTION REACTIONS; ELECTRON-TRANSFER REACTIONS; MANGANESE TRICARBONYL COMPLEXES; TENTACLED IRON SANDWICHES; RAY CRYSTAL-STRUCTURE; M = FE; ORGANOIRON COMPLEXES; METAL-COMPLEXES; REPLACEMENT REACTIONS;
Keywords:
cyclopentadienyliron; arenes; nucleophilic substitution; nucleophilic addition;
Tipo documento:
Review
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
297
Recensione:
Indirizzi per estratti:
Indirizzo: Abd-El-Aziz, AS Univ Winnipeg, Dept Chem, Winnipeg, MB R3B 2E9, Canada Univ Winnipeg Winnipeg MB Canada R3B 2E9 R3B 2E9, Canada
Citazione:
A.S. Abd-El-Aziz e S. Bernardin, "Synthesis and reactivity of arenes coordinated to cyclopentadienyliron cations", COORD CH RE, 203, 2000, pp. 219-267

Abstract

Over the past few decades, there has been tremendous interest in the chemistry of arenes coordinated to transition metal moieties due to their applications in the fields of organic and polymer synthesis. The electrophilicityof coordinated arenes allows for reactions with a number of carbon-, oxygen-, nitrogen- and sulfur-containing nucleophiles. This review describes thesynthesis and reactivity of both mono- and polyiron arene complexes, Spectroscopic and electrochemical methods for the characterization of these coordination compounds are presented. The important synthetic applications of arene cyclopentadienyliron complexes are also described. (C) 2000 Elsevier Science S.A. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 19/09/20 alle ore 09:34:14