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Titolo:
Synthetic and thermochemical studies of fluorinated tertiary phosphine ligands R2PRf [R = Cy, Ph, Pr-i; R-f = CH2CH2(CF2)(5)CF3] in an organoiron system
Autore:
Smith, DC; Klaman, AL; Cadoret, J; Nolan, SP;
Indirizzi:
Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA Univ New Orleans New Orleans LA USA 70148 Chem, New Orleans, LA 70148 USA
Titolo Testata:
INORGANICA CHIMICA ACTA
, volume: 300, anno: 2000,
pagine: 987 - 991
SICI:
0020-1693(20000430)300:<987:SATSOF>2.0.ZU;2-C
Fonte:
ISI
Lingua:
ENG
Soggetto:
SUPERCRITICAL CARBON-DIOXIDE; BENZYLIDENEACETONEIRON TRICARBONYL; L(2)FE(CO)(3) SYSTEM; OLEFIN METATHESIS; SUBSTITUTION; CATALYSIS; ENTHALPIES; COMPLEXES; CYCLOPENTADIENYL; EPOXIDATION;
Keywords:
thermochemical studies; fluorinated phosphine ligands; organoiron system; tertiary phosphine ligands;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
37
Recensione:
Indirizzi per estratti:
Indirizzo: Nolan, SP Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA Univ New Orleans New Orleans LA USA 70148 Orleans, LA 70148 USA
Citazione:
D.C. Smith et al., "Synthetic and thermochemical studies of fluorinated tertiary phosphine ligands R2PRf [R = Cy, Ph, Pr-i; R-f = CH2CH2(CF2)(5)CF3] in an organoiron system", INORG CHIM, 300, 2000, pp. 987-991

Abstract

The fluorinated phosphine ligands [PR2Rf (R = Cy (2); Pr-i, (3); Ph, (4); R-f = CH2CH2(CF2)(5)CF3] react with Fe(CO)(3)(BDA) (1) (BDA = (C6H5)CH = CHC(O)CH3, benzylideneacetone) to yield the corresponding Fe(CO)(3)(PR2Rf)(2)= (R = Cy, (5) Pr-i, (6) Ph, (7)) complexes. Infrared studies on the carbonyl complexes and solution calorimetry studies of the reaction of 1 with 2,3 and 4 have been performed to quantify the donor strength of this series of ligands. (C) 2000 Elsevier Science S.A. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 28/01/21 alle ore 07:45:54