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Titolo:
Asymmetric total synthesis of halicholactone
Autore:
Takemoto, Y; Baba, Y; Saha, G; Nakao, S; Iwata, C; Tanaka, T; Ibuka, T;
Indirizzi:
Kyoto Univ, Grad Sch Pharmaceut Sci, Sakyo Ku, Kyoto 6068501, Japan Kyoto Univ Kyoto Japan 6068501 aceut Sci, Sakyo Ku, Kyoto 6068501, Japan Osaka Univ, Grad Sch Pharmaceut Sci, Suita, Osaka 5650871, Japan Osaka Univ Suita Osaka Japan 5650871 eut Sci, Suita, Osaka 5650871, Japan
Titolo Testata:
TETRAHEDRON LETTERS
fascicolo: 19, volume: 41, anno: 2000,
pagine: 3653 - 3656
SICI:
0040-4039(20000506)41:19<3653:ATSOH>2.0.ZU;2-O
Fonte:
ISI
Lingua:
ENG
Soggetto:
CATALYTIC ENANTIOSELECTIVE ALKYLATION; HALICHONDRIA-OKADAI KADOTA; ORGANIC-SYNTHESIS; (DIENE)FE(CO)(3) COMPLEXES; NATURAL-PRODUCTS; NEOHALICHOLACTONE; ACID; STEREOCONTROL; METATHESIS; SUBSTRATE;
Keywords:
iron and compounds; cyclopropanation; ring-closing metathesis; total synthesis; halicholactone;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Life Sciences
Physical, Chemical & Earth Sciences
Citazioni:
25
Recensione:
Indirizzi per estratti:
Indirizzo: Takemoto, Y Kyoto Univ, Grad Sch Pharmaceut Sci, Sakyo Ku, Kyoto 6068501, Japan Kyoto Univ Kyoto Japan 6068501 akyo Ku, Kyoto 6068501, Japan
Citazione:
Y. Takemoto et al., "Asymmetric total synthesis of halicholactone", TETRAHEDR L, 41(19), 2000, pp. 3653-3656

Abstract

The total synthesis of halicholactone by using the chirality of (diene)Fe(CO)(3) complexes was reported. The key steps of the synthesis include catalytic asymmetric alkylation, regio- and stereoselective phenylsulfenylation,regio- and stereoselective cyclopropanation and formation of a nine-membered lactone by ring-closing metathesis. (C) 2000 Elsevier Science Ltd. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 29/09/20 alle ore 10:29:21