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Titolo:
Intramolecular binding site organization by Pd(II) complexation with a resorcin[4]arene derivative
Autore:
Lim, CW; Hong, JI;
Indirizzi:
Seoul Natl Univ, Sch Chem & Mol Engn, Seoul 151742, South Korea Seoul NatlUniv Seoul South Korea 151742 Engn, Seoul 151742, South Korea
Titolo Testata:
TETRAHEDRON LETTERS
fascicolo: 17, volume: 41, anno: 2000,
pagine: 3113 - 3117
SICI:
0040-4039(20000422)41:17<3113:IBSOBP>2.0.ZU;2-F
Fonte:
ISI
Lingua:
ENG
Soggetto:
MOLECULAR RECOGNITION; HYDROPHOBIC BINDING; AMMONIUM-COMPOUNDS; AQUEOUS-MEDIA; WATER; HOST; CYCLOPHANE; MECHANICS; CHEMISTRY; SOLVATION;
Keywords:
self-assembly; hydrophobic interaction; electrostatic interaction; resorcin[4]arene;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Life Sciences
Physical, Chemical & Earth Sciences
Citazioni:
31
Recensione:
Indirizzi per estratti:
Indirizzo: Hong, JI Seoul Natl Univ, Sch Chem & Mol Engn, Seoul 151742, South Korea Seoul Natl Univ Seoul South Korea 151742 ul 151742, South Korea
Citazione:
C.W. Lim e J.I. Hong, "Intramolecular binding site organization by Pd(II) complexation with a resorcin[4]arene derivative", TETRAHEDR L, 41(17), 2000, pp. 3113-3117

Abstract

Intramolecular assembly of a binding site by Pd(II) ion complexation with a resorcin[4]arene derivative has led to a water-soluble resorcin[4]arene receptor. The bowl-shaped cavitand host 2 shows a good binding affinity to aromatic carboxylates with alkyl moiety of an appropriate length in D2O. Theguest inclusion within the host cavity was confirmed by H-1 NMR spectroscopy. Hydrophobic and electrostatic interactions turned out to act as cooperative binding force for a strong complex formation with appropriate anionic guests in water. (C) 2000 Elsevier Science Ltd. Air rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 23/11/20 alle ore 21:32:07