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Titolo:
Synthesis and spectroscopic characterization of a Dawson trivanadium-substituted polyoxotungstate-supported {(Cp*Rh)(2)}(4+) complex; ((Bu4N)-N-n)(5)[(Cp*Rh)(2)P2W15V3O62]
Autore:
Nomiya, K; Hasegawa, T;
Indirizzi:
Kanagawa Univ, Fac Sci, Dept Mat Sci, Kanagawa 2591293, Japan Kanagawa Univ Kanagawa Japan 2591293 pt Mat Sci, Kanagawa 2591293, Japan
Titolo Testata:
CHEMISTRY LETTERS
fascicolo: 4, , anno: 2000,
pagine: 410 - 411
SICI:
0366-7022(20000405):4<410:SASCOA>2.0.ZU;2-9
Fonte:
ISI
Lingua:
ENG
Soggetto:
METAL-OXIDE ANALOGS; TRISUBSTITUTED HETEROPOLYTUNGSTATES; ORGANOMETALLIC COMPLEX; CATALYST PRECURSORS; PRECATALYSTS; DIOXYGENASE; OXYGENATION; IRIDIUM(I); RHODIUM(I);
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
18
Recensione:
Indirizzi per estratti:
Indirizzo: Nomiya, K Kanagawa Univ, Fac Sci, Dept Mat Sci, Kanagawa 2591293, Japan Kanagawa Univ Kanagawa Japan 2591293 , Kanagawa 2591293, Japan
Citazione:
K. Nomiya e T. Hasegawa, "Synthesis and spectroscopic characterization of a Dawson trivanadium-substituted polyoxotungstate-supported {(Cp*Rh)(2)}(4+) complex; ((Bu4N)-N-n)(5)[(Cp*Rh)(2)P2W15V3O62]", CHEM LETT, (4), 2000, pp. 410-411

Abstract

A novel polyoxotungstate-based 2 : 1-type Cp*Rh2+ complex, ((Bu4N)-N-n)(5)[(Cp*Rh)(2)P2W15V3O62] (Cp* = C5Me5), was synthesized by a direct reaction of the Dawson trivanadium-substituted polyoxotungstate ((Bu4N)-N-n)(9)[alpha-1,2,3-P2W15V3O62] with an equimolar amount of [Cp*RhCl2](2) in ice-cooledCH2Cl2, without use of silver(I) salts to remove the chloride ions of the precursor.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 01/12/20 alle ore 09:00:33