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Titolo:
Synthesis of porphyrins: models of natural hemoproteins and impressive catalysts for asymmetric epoxidation of olefins
Autore:
Rose, E; Quelquejeu, M; Pandian, RP; Lecas-Nawrocka, A; Vilar, A; Ricart, G; Collman, JP; Wang, Z; Straumanis, A;
Indirizzi:
Univ Paris 06, UMR 7611, Lab Synth Organ & Organomet, F-75252 Paris 5, France Univ Paris 06 Paris France 5 Organ & Organomet, F-75252 Paris 5, France USTL, Lab Spectrochim Masse, F-59655 Villeneuve Dascq, France USTL Villeneuve Dascq France F-59655 e, F-59655 Villeneuve Dascq, France Stanford Univ, Dept Chem, Stanford, CA 94305 USA Stanford Univ Stanford CA USA 94305 iv, Dept Chem, Stanford, CA 94305 USA
Titolo Testata:
POLYHEDRON
fascicolo: 5, volume: 19, anno: 2000,
pagine: 581 - 586
SICI:
0277-5387(20000315)19:5<581:SOPMON>2.0.ZU;2-V
Fonte:
ISI
Lingua:
ENG
Soggetto:
TWIN-CORONET PORPHYRINS; STRAPPED MANGANESE PORPHYRINS; PICNIC-BASKET PORPHYRINS; ENANTIOSELECTIVE EPOXIDATION; UNFUNCTIONALIZED OLEFINS; STYRENE DERIVATIVES; IRON PORPHYRINS; METALLOPORPHYRINS; HYDROXYLATION; BINDING;
Keywords:
porphyrins; hemoprotein models; chiral catalysts; epoxidation; olefins;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
40
Recensione:
Indirizzi per estratti:
Indirizzo: Rose, E Univ Paris 06, UMR 7611, Lab Synth Organ & Organomet, BP 181,4 Pl Jussieu,F-75252 Paris 5, France Univ Paris 06 BP 181,4 Pl Jussieu Paris France 5 Paris 5, France
Citazione:
E. Rose et al., "Synthesis of porphyrins: models of natural hemoproteins and impressive catalysts for asymmetric epoxidation of olefins", POLYHEDRON, 19(5), 2000, pp. 581-586

Abstract

Porphyrins, with two chiral binaphthyl handles, efficiently catalyze the epoxidation of terminal olefins to give epoxides with high enantiomeric excess and turnover number. (C) 2000 Elsevier Science Ltd All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 04/07/20 alle ore 15:06:37