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Titolo:
Inhibition of a palladium(II) catalyst upon formation of a di-mu-chloro complex: di-mu-chloro-bis[1,2-bis(diphenylphosphino)ethane-P,P ']-dipalladium(II) bis(tetrafluoroborate) bis(deuterochloroform) solvate
Autore:
Abu-Surrah, AS; Klinga, M; Repo, T; Leskela, M; Debaerdemaeker, T; Rieger, B;
Indirizzi:
Univ Helsinki, Dept Chem, FIN-00014 Helsinki, Finland Univ Helsinki Helsinki Finland FIN-00014 em, FIN-00014 Helsinki, Finland Univ Ulm, Sekt Rontgen & Elektronenbeugung, D-89069 Ulm, Germany Univ UlmUlm Germany D-89069 n & Elektronenbeugung, D-89069 Ulm, Germany
Titolo Testata:
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
, volume: 56, anno: 2000,
parte:, 2
pagine: E44 - E45
SICI:
0108-2701(200002)56:<E44:IOAPCU>2.0.ZU;2-P
Fonte:
ISI
Lingua:
ENG
Soggetto:
MOLECULAR-WEIGHT; CARBON-MONOXIDE; ALTERNATING COPOLYMERIZATION; PROPENE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
11
Recensione:
Indirizzi per estratti:
Indirizzo: Abu-Surrah, AS Univ Helsinki, Dept Chem, Box 55, FIN-00014 Helsinki, Finland Univ Helsinki Box 55 Helsinki Finland FIN-00014 i, Finland
Citazione:
A.S. Abu-Surrah et al., "Inhibition of a palladium(II) catalyst upon formation of a di-mu-chloro complex: di-mu-chloro-bis[1,2-bis(diphenylphosphino)ethane-P,P ']-dipalladium(II) bis(tetrafluoroborate) bis(deuterochloroform) solvate", ACT CRYST C, 56, 2000, pp. E44-E45

Abstract

The title compound was formed upon slow evaporation of a solution of the solvated dicationic complex bis(acetonitrile)-bis[1,2-bis(diphenyl-phosphino)ethane]palladium(II) bis-(tetrafluoroborate) in deuterated chloroform. Thedinucleur palladium complex forms triclinic crystals and there is an inversion center between the Pd atoms. Compared to the corresponding monomeric compound, the Cl-Pd-Cl angles decrease upon briding from 94.19 (7) to 86.96 (4)degrees.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 30/10/20 alle ore 00:35:38