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Titolo:
An alkyl-palladium(II) complex with a bidentate phosphine ligand: [1,3-bis(diphenylphosphino)propane-P,P ']dimethylpalladium(II) toluene hemisolvate
Autore:
Abu-Surrah, AS; Debaerdemaeker, T; Huhn, W; Rieger, B; Klinga, M; Repo, T; Leskela, M;
Indirizzi:
Univ Helsinki, Dept Chem, Inorgan Chem Lab, FIN-00014 Helsinki, Finland Univ Helsinki Helsinki Finland FIN-00014 ab, FIN-00014 Helsinki, Finland Univ Ulm, Sekt Rontgen & Elektronenbeugung, D-89069 Ulm, Germany Univ UlmUlm Germany D-89069 n & Elektronenbeugung, D-89069 Ulm, Germany Univ Ulm, D-89081 Ulm, Germany Univ Ulm Ulm Germany D-89081Univ Ulm, D-89081 Ulm, Germany
Titolo Testata:
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
, volume: 56, anno: 2000,
parte:, 2
pagine: E42 - E43
SICI:
0108-2701(200002)56:<E42:AACWAB>2.0.ZU;2-2
Fonte:
ISI
Lingua:
ENG
Soggetto:
METHYL COMPLEXES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
12
Recensione:
Indirizzi per estratti:
Indirizzo: Abu-Surrah, AS Univ Helsinki, Dept Chem, Inorgan Chem Lab, POB 55, FIN-00014 Helsinki, Finland Univ Helsinki POB 55 Helsinki Finland FIN-00014 i, Finland
Citazione:
A.S. Abu-Surrah et al., "An alkyl-palladium(II) complex with a bidentate phosphine ligand: [1,3-bis(diphenylphosphino)propane-P,P ']dimethylpalladium(II) toluene hemisolvate", ACT CRYST C, 56, 2000, pp. E42-E43

Abstract

In the title compound, [Pd(CH3)(2)(C27H26P2)]. 0.5C(7)H(8), the Pd atom isat the centre of an approximately square-planar arrangement of two P atomsand two methyl groups. The P-Pd-P angle [93.19 (3)degrees] is significantly larger than that in the corresponding dichloride complex [Pd(dppp)Cl-2]. The toluene molecule is disordered across an inversion centre.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 27/09/20 alle ore 05:47:21