Catalogo Articoli (Spogli Riviste)

OPAC HELP

Titolo:
Enantioresolution of aliphatic alcohols by lithocholamide
Autore:
Aoki, Y; Hishikawa, Y; Sada, K; Miyata, M;
Indirizzi:
Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan Osaka Univ Suita Osaka Japan 5650871 ife Sci, Suita, Osaka 5650871, Japan
Titolo Testata:
ENANTIOMER
fascicolo: 1, volume: 5, anno: 2000,
pagine: 95 - 104
SICI:
1024-2430(2000)5:1<95:EOAABL>2.0.ZU;2-Y
Fonte:
ISI
Lingua:
ENG
Soggetto:
INCLUSION-COMPOUNDS; CHIRAL RECOGNITION; OPTICAL RESOLUTION; HOST; ACID;
Keywords:
enantioresolution; lithocholamide; inclusion compounds; chiral recognition; aliphatic alcohols;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
16
Recensione:
Indirizzi per estratti:
Indirizzo: Miyata, M Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, 2-1 Yamadaoka, Suita, Osaka 5650871, Japan Osaka Univ 2-1 Yamadaoka Suita Osaka Japan 5650871 650871, Japan
Citazione:
Y. Aoki et al., "Enantioresolution of aliphatic alcohols by lithocholamide", ENANTIOMER, 5(1), 2000, pp. 95-104

Abstract

Lithocholamide (LCAM) forms inclusion compounds with aliphatic alcohols involving over five carbon atoms. Enantioresolution of the racemic alcohols was studied in channels of the inclusion compounds. X-ray crystallographic study clarified that host assemblies exhibit guest-dependent polymorphism. In each polymorphic crystal, the more longer or bulkier groups the alcohols have, the effective the resolutions become. The inclusion spaces were analyzed by a computed tomographic method, explaining the chiral recognition mechanism from a stereochemical viewpoint.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 04/04/20 alle ore 12:24:06