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Titolo:
Oxidation of thioethers and sulfoxides with hydrogen peroxide using TS-1 as catalyst
Autore:
Robinson, DJ; Davies, L; McGuire, N; Lee, DF; McMorn, P; Willock, DJ; Watson, GW; Page, PCB; Bethell, D; Hutchings, GJ;
Indirizzi:
Univ Liverpool, Leverhulme Ctr Innovat Catalysis, Dept Chem, Liverpool L693BX, Merseyside, England Univ Liverpool Liverpool Merseyside England L69 3BX , Merseyside, England Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales Cardiff Univ Cardiff S Glam Wales CF10 3TB ardiff CF10 3TB, S Glam, Wales Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England Univ Loughborough Loughborough Leics England LE11 3TU 3TU, Leics, England
Titolo Testata:
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
fascicolo: 7, volume: 2, anno: 2000,
pagine: 1523 - 1529
SICI:
1463-9076(2000)2:7<1523:OOTASW>2.0.ZU;2-O
Fonte:
ISI
Lingua:
ENG
Soggetto:
TI-CONTAINING ZEOLITES; SELECTIVE OXIDATION; MOLECULAR-SIEVE; TITANIUM SILICALITE; ALLYL ALCOHOL; EPOXIDATION; BETA; SULFIDES; SULFONES; ACIDITY;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
31
Recensione:
Indirizzi per estratti:
Indirizzo: Robinson, DJ Univ Liverpool, Leverhulme Ctr Innovat Catalysis, Dept Chem, Liverpool L693BX, Merseyside, England Univ Liverpool Liverpool Merseyside England L69 3BX England
Citazione:
D.J. Robinson et al., "Oxidation of thioethers and sulfoxides with hydrogen peroxide using TS-1 as catalyst", PHYS CHEM P, 2(7), 2000, pp. 1523-1529

Abstract

A combined experimental and molecular simulation study of the oxidation ofthioethers with hydrogen peroxide using Ti-containing zeolites as catalysts is described and discussed. Two aspects of reaction selectivity were explored. First, regioselectivity was studied for the oxidation of allyl methylthioether with TS-1 as catalyst, and only products for the oxidation at sulfur, i.e., the sulfoxide and sulfone, were observed. Second, shape-selective oxidation was studied using four isomeric butyl methyl thioethers. For n-, iso- and sec-butyl methyl thioethers the dominant product in the TS-1 catalysed reaction was the sulfone, but for tert-butyl methyl thioether, the dominant product was from partial oxidation to the sulfoxide. Molecular simulations were used to investigate the origin of this effect. For all substrates used in this study, the oxidation of the thioether to the sulfoxide was found to occur readily by a non-catalysed solution reaction and this was studied in detail. However, the oxidation of the sulfoxide to the sulfone was only observed in the catalysed reactions. It was observed that the non-catalysed reaction can be suppressed by carrying out the catalysed reaction in the presence of a base, 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), that is too large to diffuse into the intracrystalline pore structure of TS-1. Inthe presence of DBU, the rate of reaction with TS-1 as catalyst was much lower and the relative ratios of the sulfoxide and sulfone products can be explained through a combination of intramolecular steric hindrance and the shape selectivity of the zeolite.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 25/09/20 alle ore 13:39:13