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Titolo:
Predicting the gas-liquid critical point from the second virial coefficient
Autore:
Vliegenthart, GA; Lekkerkerker, HNW;
Indirizzi:
Univ Utrecht, Debye Inst, Vant Hoff Lab Phys & Colloid Chem, NL-3584 CH Utrecht, Netherlands Univ Utrecht Utrecht Netherlands NL-3584 CH 3584 CH Utrecht, Netherlands
Titolo Testata:
JOURNAL OF CHEMICAL PHYSICS
fascicolo: 12, volume: 112, anno: 2000,
pagine: 5364 - 5369
SICI:
0021-9606(20000322)112:12<5364:PTGCPF>2.0.ZU;2-5
Fonte:
ISI
Lingua:
ENG
Soggetto:
RIGID C-60 MOLECULES; ATTRACTIVE-YUKAWA SYSTEM; MONTE-CARLO SIMULATION; LENS PROTEIN SOLUTIONS; PHASE-DIAGRAM; LYSOZYME SOLUTIONS; CRITICAL-BEHAVIOR; SIMPLE FLUIDS; CRYSTAL NUCLEATION; POLYMER MIXTURES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
63
Recensione:
Indirizzi per estratti:
Indirizzo: Vliegenthart, GA Univ Utrecht, Debye Inst, Vant Hoff Lab Phys & Colloid Chem, Padualaan 8, NL-3584 CH Utrecht, Netherlands Univ Utrecht Padualaan 8 Utrecht Netherlands NL-3584 CH
Citazione:
G.A. Vliegenthart e H.N.W. Lekkerkerker, "Predicting the gas-liquid critical point from the second virial coefficient", J CHEM PHYS, 112(12), 2000, pp. 5364-5369

Abstract

We show that whereas the critical point is very sensitive to the range of interaction, the second virial coefficient has a fairly constant value at the critical temperature. This enables us to predict the critical temperature with fair accuracy. We discuss the connection between the second virial coefficient as a predictor for the critical temperature and the second virial coefficient as predictor in crystal growth as was proposed by George and Wilson [A. George and W. W. Wilson, Acta Crystallogr., Sec. D: Biol. Crystallogr. 50, 361 (1994)]. (C) 2000 American Institute of Physics. [S0021-9606(00)51212-4].

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Documento generato il 30/09/20 alle ore 09:33:14