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Titolo:
A new family of dimolybdenum compounds with cyanide and phosphine ligands
Autore:
Szalay, PS; Dunbar, KR;
Indirizzi:
Texas A&M Univ, Dept Chem, College Stn, TX 77845 USA Texas A&M Univ College Stn TX USA 77845 t Chem, College Stn, TX 77845 USA
Titolo Testata:
INORGANIC CHEMISTRY COMMUNICATIONS
fascicolo: 2, volume: 3, anno: 2000,
pagine: 49 - 51
SICI:
1387-7003(200002)3:2<49:ANFODC>2.0.ZU;2-Z
Fonte:
ISI
Lingua:
ENG
Soggetto:
METAL MULTIPLE BONDS; CHEMISTRY; COMPLEXES;
Keywords:
dimolybdenum(II,II) complex; dimolybdenum(II,III) complex; cyanide complexes; crystal structures;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
12
Recensione:
Indirizzi per estratti:
Indirizzo: Dunbar, KR Texas A&M Univ, Dept Chem, College Stn, TX 77845 USA Texas A&M Univ College Stn TX USA 77845 lege Stn, TX 77845 USA
Citazione:
P.S. Szalay e K.R. Dunbar, "A new family of dimolybdenum compounds with cyanide and phosphine ligands", INORG CH C, 3(2), 2000, pp. 49-51

Abstract

Reaction of Mo2Cl4(dppm)(2) with excess [n-Bu4N][CN] produces [Bu4N](2)[Mo-2(II,II)(CN)(6)(dppm)(2)]. 2(CH3CN). 2(C6H6) (1) the first example of an edge-sharing bioctahedral compound of Mo(II), that upon exposure to air oxidizes to the mixed valence analog [Bu4N][Mo-2(II,III)(CN)(6)(dppm)(2)]. 2(H2O). 2(CH3CN) (2). (C) 2000 Elsevier Science S.A. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 04/04/20 alle ore 11:07:32