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Titolo:
Preparation and catalysis of NaY-encapsulated Mn(III) Schiff-base complex in presence of molecular oxygen
Autore:
Wang, RM; Feng, HX; He, YF; Xia, CG; Suo, JS; Wang, YP;
Indirizzi:
NW Normal Univ, Dept Chem, Lanzhou 730070, Peoples R China NW Normal UnivLanzhou Peoples R China 730070 ou 730070, Peoples R China Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key lab Oxo Synth & SelectOxidat, Lanzhou 730000, Peoples R China Chinese Acad Sci Lanzhou Peoples R China 730000 730000, Peoples R China
Titolo Testata:
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
fascicolo: 1-2, volume: 151, anno: 2000,
pagine: 253 - 259
SICI:
1381-1169(20000215)151:1-2<253:PACONM>2.0.ZU;2-E
Fonte:
ISI
Lingua:
ENG
Soggetto:
AEROBIC EPOXIDATION; PARTIAL OXIDATION; ALKENES; OLEFINS; PORPHYRIN; MECHANISM; ETHERS; O2;
Keywords:
epoxidation; zeolite encapsulated catalyst; Mn-Schiff-base;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
23
Recensione:
Indirizzi per estratti:
Indirizzo: Wang, RM NW Normal Univ, Dept Chem, Lanzhou 730070, Peoples R China NW Normal Univ Lanzhou Peoples R China 730070 , Peoples R China
Citazione:
R.M. Wang et al., "Preparation and catalysis of NaY-encapsulated Mn(III) Schiff-base complex in presence of molecular oxygen", J MOL CAT A, 151(1-2), 2000, pp. 253-259

Abstract

The new NaY zeolite (DMY), whose cages' size had been expanded, was used as supports for encapsulating the large Schiff-base complexes. The catalystswere used in the aerobic epoxidation of 1-octene. The catalyst showed highactivity and selectivity for the substrate and products. These catalysts proved to be more active than other kind of metal ion or supports. The effect of temperature, organic acid or base, and the amount of catalyst was discussed. (C) 2000 Elsevier Science B.V. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 28/09/20 alle ore 14:49:07