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Titolo:
An electrochemical and Fourier transform infrared spectroscopic study of the aqueous oxidation of quadricyclane and nortricyclanol
Autore:
White, K; Buttry, DA;
Indirizzi:
Univ Wyoming, Dept Chem, Laramie, WY 82071 USA Univ Wyoming Laramie WY USA 82071 oming, Dept Chem, Laramie, WY 82071 USA
Titolo Testata:
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
fascicolo: 1, volume: 147, anno: 2000,
pagine: 266 - 271
SICI:
0013-4651(200001)147:1<266:AEAFTI>2.0.ZU;2-9
Fonte:
ISI
Lingua:
ENG
Soggetto:
VALENCE ISOMERIZATION; ALIPHATIC-ALCOHOLS; RADICAL CATIONS; NORBORNADIENE; ELECTROCATALYSIS; CONVERSION; ADSORPTION; OXIDES; GOLD; ESR;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Engineering, Computing & Technology
Citazioni:
31
Recensione:
Indirizzi per estratti:
Indirizzo: White, K Univ Wyoming, Dept Chem, Laramie, WY 82071 USA Univ Wyoming Laramie WY USA 82071 pt Chem, Laramie, WY 82071 USA
Citazione:
K. White e D.A. Buttry, "An electrochemical and Fourier transform infrared spectroscopic study of the aqueous oxidation of quadricyclane and nortricyclanol", J ELCHEM SO, 147(1), 2000, pp. 266-271

Abstract

The aqueous redox chemistry of quadricyclo(2.2.1.0(2.6).0(3.5))heptane. commonly known as quadricyclane, and its environmentally important hydrolysisproduct, nortricyclanol, was investigated through the use of cyclic voltammetry, chronocoulometry, and rotating disk electrochemical methods. Oxidation of both compounds in aqueous environments yields polymeric films that rapidly foul the working electrode. A novel experimental approach was developed to circumvent the problems associated with the formation of the fouling films, which were further characterized using attenuated total reflectance infrared spectroscopy. (C) 2000 The Electrochemical Society. S0013-4651(99)01-062-9. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 28/03/20 alle ore 23:28:09