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Titolo:
Stereospecific synthesis of piperidine skeleton by [4+2] cycloaddition, leading to the synthesis of piperidines of biological interests
Autore:
Shimizu, M; Arai, A; Fujisawa, T;
Indirizzi:
Mie Univ, Dept Chem Mat, Tsu, Mie 5148507, Japan Mie Univ Tsu Mie Japan 5148507 iv, Dept Chem Mat, Tsu, Mie 5148507, Japan
Titolo Testata:
HETEROCYCLES
fascicolo: 1, volume: 52, anno: 2000,
pagine: 137 - 140
SICI:
0385-5414(20000101)52:1<137:SSOPSB>2.0.ZU;2-P
Fonte:
ISI
Lingua:
ENG
Soggetto:
BETA-LACTAM SKELETONS; DIELS-ALDER REACTION; CHIRAL IMINE; STEREOCONTROLLED CONSTRUCTION; CONDENSATION; ACID; DIENE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
18
Recensione:
Indirizzi per estratti:
Indirizzo: Shimizu, M Mie Univ, Dept Chem Mat, Tsu, Mie 5148507, Japan Mie Univ Tsu Mie Japan 5148507 em Mat, Tsu, Mie 5148507, Japan
Citazione:
M. Shimizu et al., "Stereospecific synthesis of piperidine skeleton by [4+2] cycloaddition, leading to the synthesis of piperidines of biological interests", HETEROCYCLE, 52(1), 2000, pp. 137-140

Abstract

[4+2] Cycloaddition reaction between a chiral imine possessing an auxiliary derived from tartaric acid and Danishefsky diene was studied, and the reaction promoted by boron trifluoride etherate gave 2,3-dehydropiperidin-4-one in a stereospecific manner. The adduct thus obtained was converted into (S)-coniine derivatives without loss of the stereochemical integrity.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 26/09/20 alle ore 14:42:53