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Titolo:
Influence of charge fluctuations on the critical behavior of electrolyte solutions
Autore:
Koulinskii, VL; Malomuzh, NP; Tolpekin, VA;
Indirizzi:
Odessa State Univ, Dept Theoret Phys, UA-270100 Odessa, Ukraine Odessa State Univ Odessa Ukraine UA-270100 ys, UA-270100 Odessa, Ukraine
Titolo Testata:
PHYSICAL REVIEW E
fascicolo: 6, volume: 60, anno: 1999,
parte:, B
pagine: 6897 - 6905
SICI:
1063-651X(199912)60:6<6897:IOCFOT>2.0.ZU;2-4
Fonte:
ISI
Lingua:
ENG
Soggetto:
DOUBLE CRITICAL-POINT; IONIC FLUIDS; COULOMBIC CRITICALITY; GINZBURG CRITERION; CROSSOVER-BEHAVIOR; CRITICAL EXPONENT; SODIUM-CHLORIDE; NACL;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
--discip_EC--
Citazioni:
34
Recensione:
Indirizzi per estratti:
Indirizzo: Koulinskii, VL Odessa State Univ, Dept Theoret Phys, 2 Petra Velikogo, UA-270100 Odessa, Ukraine Odessa State Univ 2 Petra Velikogo Odessa Ukraine UA-270100
Citazione:
V.L. Koulinskii et al., "Influence of charge fluctuations on the critical behavior of electrolyte solutions", PHYS REV E, 60(6), 1999, pp. 6897-6905

Abstract

The effective Hamiltonian of electrolyte solution near its critical point is constructed. The vapor-liquid critical point is investigated in derail. The strong dependence of the Landau-Ginsburg number on the concentration ofelectrolyte is demonstrated. It is shown that the charge fluctuations in electrolytes essentially suppress the fluctuation of the order parameter andbroaden the region of classical behavior. [S1063-651X(99)02411-3].

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Documento generato il 06/04/20 alle ore 08:29:33