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Titolo:
Ru(CH3CN)(3)Cl-3, preparation and use as a mediator for the electrooxidation of hydrocarbons
Autore:
Appelbaum, L; Heinrichs, C; Demtschuk, J; Michman, M; Oron, M; Schafer, HJ; Schumann, H;
Indirizzi:
Hebrew Univ Jerusalem, Dept Organ Chem, IL-91904 Jerusalem, Israel Hebrew Univ Jerusalem Jerusalem Israel IL-91904 -91904 Jerusalem, Israel Univ Munster, Inst Organ Chem, D-48148 Munster, Germany Univ Munster Munster Germany D-48148 rgan Chem, D-48148 Munster, Germany Tech Univ Berlin, Inst Anorgan & Analyt Chem, D-10623 Berlin, Germany TechUniv Berlin Berlin Germany D-10623 yt Chem, D-10623 Berlin, Germany
Titolo Testata:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
fascicolo: 2, volume: 592, anno: 1999,
pagine: 240 - 250
SICI:
0022-328X(199912)592:2<240:RPAUAA>2.0.ZU;2-5
Fonte:
ISI
Lingua:
ENG
Soggetto:
INDIRECT ANODIC-OXIDATION; MIXED HALIDE NITRILE; ELECTROCHEMICAL OXIDATION; REDUCTION; COMPLEXES; CATALYSIS; RADICALS; RUTHENIUM(II); MECHANISM; ALDEHYDES;
Keywords:
tris(acetonitrile)ruthenium trichloride; electrocatalysis; indirect electrooxidation; tetralin; tetralone;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
55
Recensione:
Indirizzi per estratti:
Indirizzo: Michman, M Hebrew Univ Jerusalem, Dept Organ Chem, IL-91904 Jerusalem, Israel Hebrew Univ Jerusalem Jerusalem Israel IL-91904 salem, Israel
Citazione:
L. Appelbaum et al., "Ru(CH3CN)(3)Cl-3, preparation and use as a mediator for the electrooxidation of hydrocarbons", J ORGMET CH, 592(2), 1999, pp. 240-250

Abstract

Hydrogenation of ruthenium chloride in acetonitrile yields complexes of the type Ru(CH3CN)(n)Cl6-n of which three are isolated (n = 2, 3, 4). Their formation is traced by voltammetry. Ru(CH3CN)(2)Cl-4 and Ru(CH3CN)(3)Cl-3 have been characterized by single-crystal X-ray diffraction. Voltammetry shows that Ru(CH3CN)(3)Cl-3 acts as a mediator for oxidation of cyclohexene, methylcyclohexene, 1-tetralol and tetralin. Its role in tetralin oxidation isillustrated by preparative scale electrolysis. The compounds Ru(CH3CN)(2)Cl-4 and Ru(CH3CN)(4)Cl-2 did not react with any of the mentioned hydrocarbons. (C) 1999 Elsevier Science S.A. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 30/10/20 alle ore 23:58:56