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Titolo:
Stereospecific 1,3-migration of an Fe(CO)(3) group on acyclic conjugated trienes bearing an electron-withdrawing group
Autore:
Takemoto, Y; Ishii, K; Miwa, Y; Taga, T; Ibuka, T; Nakao, S; Tanaka, T;
Indirizzi:
Kyoto Univ, Grad Sch Pharmaceut Sci, Sakyo Ku, Kyoto 6068501, Japan Kyoto Univ Kyoto Japan 6068501 aceut Sci, Sakyo Ku, Kyoto 6068501, Japan Osaka Univ, Grad Sch Pharmaceut Sci, Osaka 5650871, Japan Osaka Univ Osaka Japan 5650871 Sch Pharmaceut Sci, Osaka 5650871, Japan
Titolo Testata:
TETRAHEDRON LETTERS
fascicolo: 1, volume: 41, anno: 2000,
pagine: 85 - 88
SICI:
0040-4039(20000101)41:1<85:S1OAFG>2.0.ZU;2-7
Fonte:
ISI
Lingua:
ENG
Soggetto:
REMOTE ASYMMETRIC INDUCTION; STEREOSELECTIVE SYNTHESIS; TRICARBONYL COMPLEXES; REACTIVITY; 1,2-MIGRATION; CONFIGURATION; ISOMERIZATION; UTILITY; MOIETY;
Keywords:
asymmetric induction; trienes; iron; iron compounds; isomerization;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Life Sciences
Physical, Chemical & Earth Sciences
Citazioni:
33
Recensione:
Indirizzi per estratti:
Indirizzo: Tanaka, T Kyoto Univ, Grad Sch Pharmaceut Sci, Sakyo Ku, Kyoto 6068501, Japan Kyoto Univ Kyoto Japan 6068501 Sakyo Ku, Kyoto 6068501, Japan
Citazione:
Y. Takemoto et al., "Stereospecific 1,3-migration of an Fe(CO)(3) group on acyclic conjugated trienes bearing an electron-withdrawing group", TETRAHEDR L, 41(1), 2000, pp. 85-88

Abstract

Treatment of acyclic conjugated (eta(4)-4-7)-triene Fe(CO)(3) complexes bearing an electron-withdrawing group at a terminal position with a base suchas KN(SiMe3)(2) and NaH promoted 1,3-migration of an Fe(CO)(3) group on the triene, giving (eta(4)-2-5)-triene Fe(CO)(3) complexes. The 1,3-migrationof an Fe(CO)(3) group is revealed to proceed in a stereospecific manner. (C) 1999 Elsevier Science Ltd. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 29/09/20 alle ore 00:43:29