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Titolo:
Electrochemical desorption of binary self-assembled monolayers of butyl hexadecyl disulfide on Au(111) electrodes
Autore:
Azehara, H; Yoshimoto, S; Hokari, H; Akiba, U; Taniguchi, I; Fujihira, M;
Indirizzi:
Tokyo Inst Technol, Dept Biomol Engn, Midori Ku, Yokohama, Kanagawa 2268501, Japan Tokyo Inst Technol Yokohama Kanagawa Japan 2268501 anagawa 2268501, Japan Kumamoto Univ, Fac Engn, Dept Appl Chem & Biochem, Kumamoto 8608555, JapanKumamoto Univ Kumamoto Japan 8608555 & Biochem, Kumamoto 8608555, Japan
Titolo Testata:
ELECTROCHEMISTRY
fascicolo: 12, volume: 67, anno: 1999,
pagine: 1227 - 1230
SICI:
1344-3542(199912)67:12<1227:EDOBSM>2.0.ZU;2-H
Fonte:
ISI
Lingua:
ENG
Soggetto:
SCANNING-TUNNELING-MICROSCOPY; PHASE-SEPARATION; CYTOCHROME-C; GOLD; SURFACES; ALKANETHIOLS;
Keywords:
asymmetrical disulfides; binary self-assembled monolayers; electrochemical desorption; Au(111);
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Engineering, Computing & Technology
Citazioni:
17
Recensione:
Indirizzi per estratti:
Indirizzo: Fujihira, M Tokyo Inst Technol, Dept Biomol Engn, Midori Ku, 4259 Nagatsuta, Yokohama,Kanagawa 2268501, Japan Tokyo Inst Technol 4259 Nagatsuta Yokohama Kanagawa Japan 2268501
Citazione:
H. Azehara et al., "Electrochemical desorption of binary self-assembled monolayers of butyl hexadecyl disulfide on Au(111) electrodes", ELECTROCH, 67(12), 1999, pp. 1227-1230

Abstract

Reductive desorption of self-assembled monolayers (SAMs) on Au(111) electrodes prepared in butyl hexadecyl disulfide solutions was studied by cyclic voltammetry. It was shown that behavior of the reductive desorption strongly depended on the concentrations of the disulfide solution. It was concluded from this observation that homogeneously mixed binary SAMs were formed atthe high concentration of the asymmetrical disulfide, while the phase-separated mixed SAMs were formed at the low concentration.

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Documento generato il 25/11/20 alle ore 03:16:09