Catalogo Articoli (Spogli Riviste)

OPAC HELP

Titolo:
Reactivity of silyl monomers for the oxidative polymerization of phenyleneunits
Autore:
Bouachrine, M; Lere-Porte, JP; Moreau, JJE;
Indirizzi:
ENSCM, Lab Chim Organomet, CNRS, F-34296 Montpellier 05, France ENSCM Montpellier France 05 anomet, CNRS, F-34296 Montpellier 05, France
Titolo Testata:
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
, volume: 152, anno: 1999,
pagine: 265 - 278
SICI:
1042-6507(1999)152:<265:ROSMFT>2.0.ZU;2-V
Fonte:
ISI
Lingua:
ENG
Soggetto:
ELECTROCHEMICAL PREPARATION; THIOPHENE; ELECTROPOLYMERIZATION; POLYTHIOPHENE; SUBSTITUENTS; POLYMERS; SILICON;
Keywords:
N-n-butylcarbazole; 1,4-dihexoxybenzene; oxidative coupling; activation; trimethylsilyl;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
35
Recensione:
Indirizzi per estratti:
Indirizzo: Moreau, JJE ENSCM, Lab Chim Organomet, CNRS, ESA 5076,8 Rue Ecole Normale,F-34296 Montpellier 05, France ENSCM ESA 5076,8 Rue Ecole Normale Montpellier France 05 ance
Citazione:
M. Bouachrine et al., "Reactivity of silyl monomers for the oxidative polymerization of phenyleneunits", PHOSPHOR SU, 152, 1999, pp. 265-278

Abstract

Oxidative coupling of silyl monomers containing phenylene units was performed electrochemically and chemically using FeCl3 as oxidant. 2,5-Trimethylsilyl-1,1-dihexoxybenzene led to poly (2,5-dihexoxyparaphenylene) with a degree of polymerization higher than the one obtained upon oxdative coupling of non silyl monomers. The coupling reaction was however moderately improvedin the case of 3,6-bis-dimethylsilyl(N-n-butylcarbazole). The role of the silyl Substituents during the oxidative polymerization is discussed.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 29/09/20 alle ore 20:26:41