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Titolo:
Radicals from epoxides. Intramolecular addition to aldehyde and ketone carbonyls
Autore:
Fernandez-Mateos, A; de la Nava, EM; Coca, GP; Silvo, AR; Gonzalez, RR;
Indirizzi:
Univ Salamanca, Fac Quim, Dept Quim Organ, E-37008 Salamanca, Spain Univ Salamanca Salamanca Spain E-37008 m Organ, E-37008 Salamanca, Spain
Titolo Testata:
ORGANIC LETTERS
fascicolo: 4, volume: 1, anno: 1999,
pagine: 607 - 609
SICI:
1523-7060(19990826)1:4<607:RFEIAT>2.0.ZU;2-A
Fonte:
ISI
Lingua:
ENG
Soggetto:
CYCLIZATIONS; KINETICS; ALKYL;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
15
Recensione:
Indirizzi per estratti:
Indirizzo: Fernandez-Mateos, A Univ Salamanca, Fac Quim, Dept Quim Organ, Pl Los Caidos 1-5, E-37008 Salamanca, Spain Univ Salamanca Pl Los Caidos 1-5 Salamanca Spain E-37008
Citazione:
A. Fernandez-Mateos et al., "Radicals from epoxides. Intramolecular addition to aldehyde and ketone carbonyls", ORG LETT, 1(4), 1999, pp. 607-609

Abstract

[GRAPHICS]Titanocene chloride reacts with epoxides by C-O homolysis with clean regioselectivity. The resultant radicals undergo intramolecular addition to aldehyde and ketone carbonyls to afford cycloalkanols in good yields. The behavior of epoxy alcohols with titanocene chloride to afford saturated diols and epoxy esters that give unsaturated hydroxy esters deserve special mention.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 08/04/20 alle ore 23:53:52