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Titolo:
Non-conventional hydrolase chemistry: Amide and carbamate bond formation catalyzed by lipases
Autore:
Gotor, V;
Indirizzi:
Univ Oviedo, Fac Quim, Dept Quim Organ & Inorgan, E-33071 Oviedo, Spain Univ Oviedo Oviedo Spain E-33071 Organ & Inorgan, E-33071 Oviedo, Spain
Titolo Testata:
BIOORGANIC & MEDICINAL CHEMISTRY
fascicolo: 10, volume: 7, anno: 1999,
pagine: 2189 - 2197
SICI:
0968-0896(199910)7:10<2189:NHCAAC>2.0.ZU;2-E
Fonte:
ISI
Lingua:
ENG
Soggetto:
PSEUDOMONAS-CEPACIA LIPASE; OPTICALLY-ACTIVE AMIDES; AMINO-ACID-ESTERS; ORGANIC-SOLVENTS; ENZYMATIC-SYNTHESIS; KINETIC RESOLUTION; CANDIDA-ANTARCTICA; ENANTIOSELECTIVE ACYLATION; CHEMOENZYMATIC SYNTHESIS; SECONDARY ALCOHOLS;
Keywords:
enzymes; lipases; amines; ammonolysis; aminolysis; alkoxycarbonylation; amides; carbamates; biocatalysis; biotransformations;
Tipo documento:
Review
Natura:
Periodico
Settore Disciplinare:
Life Sciences
Citazioni:
104
Recensione:
Indirizzi per estratti:
Indirizzo: Gotor, V Univ Oviedo, Fac Quim, Dept Quim Organ & Inorgan, E-33071 Oviedo,Spain Univ Oviedo Oviedo Spain E-33071 Inorgan, E-33071 Oviedo, Spain
Citazione:
V. Gotor, "Non-conventional hydrolase chemistry: Amide and carbamate bond formation catalyzed by lipases", BIO MED CH, 7(10), 1999, pp. 2189-2197

Abstract

Biocatalysis in nonaqueous media is becoming increasingly important in organic synthesis. Lipases are the most used enzymes, especially in transesterification reactions. However, in the last years the amidation reaction catalyzed by lipases has also been shown to be a useful tool for the organic chemists. In this review, we discuss the possibilities of the enzymatic aminolysis and ammonolysis reactions for the preparation of different amides andfor the resolution of eaters, amines and aminoalcohols. The enzymatic alkoxycarbonylation of amines opens a new way for the synthesis of chiral carbamates. (C) 1999 Elsevier Science Ltd. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 28/11/20 alle ore 04:34:25