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Titolo:
Solid-state coordination chemistry of metal oxides: Hydrothermal synthesisand structural characterization of o-phenanthroline-ligated copper- and zinc-molybdenum oxides
Autore:
Hagrman, PJ; Zubieta, J;
Indirizzi:
Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA Syracuse Univ Syracuse NY USA 13244 iv, Dept Chem, Syracuse, NY 13244 USA
Titolo Testata:
INORGANIC CHEMISTRY
fascicolo: 20, volume: 38, anno: 1999,
pagine: 4480 - 4485
SICI:
0020-1669(19991004)38:20<4480:SCCOMO>2.0.ZU;2-H
Fonte:
ISI
Lingua:
ENG
Soggetto:
INORGANIC/ORGANIC COMPOSITE-SOLIDS; ORGANOMETALLIC GROUPS; CATALYST PRECURSORS; CLUSTERS; COMPLEXES; BIOMATERIALS; PHOSPHATES; IRIDIUM(I); RHODIUM(I); MECHANISM;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
49
Recensione:
Indirizzi per estratti:
Indirizzo: Zubieta, J Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA Syracuse UnivSyracuse NY USA 13244 em, Syracuse, NY 13244 USA
Citazione:
P.J. Hagrman e J. Zubieta, "Solid-state coordination chemistry of metal oxides: Hydrothermal synthesisand structural characterization of o-phenanthroline-ligated copper- and zinc-molybdenum oxides", INORG CHEM, 38(20), 1999, pp. 4480-4485

Abstract

The hydrothermal chemistry of molybdate with phenanthroline in the presence of M(II) cations was investigated. With Cu(II) starting materials, modifications in reaction conditions yielded the molecular cluster [Cu(o-phen)(2)Mo4O13] (MOXI-27) and one-dimensional [Cu(o-phen)MoO4]. H2O (MOXI-28). The analogous Zn(II)-containing one-dimensional material [Zn(o-phen)MoO4] (MOXI-29) was isolated under conditions similar to those employed for the preparation of MOXI-28. Crystal data: C24H16CuMo4N4O13 (MOXI-27), monoclinic, P2(1)/c, a = 10.5218(3) Angstrom, b = 12.1113(4) Angstrom, c = 22.0125(7) Angstrom, beta = 97.988(1)degrees, Z = 4; C12H10CuMoN2O5 (MOXI-28), monoclinic,P2(1)/n, a = 14.050(1) Angstrom, b = 5.8818(4) Angstrom, c = 16.227(1) Angstrom, beta = 103.586(1)degrees, Z = 4; C12H8MoN2O4Zn (MOXI-29), monoclinic, P2(1)/m, n = 8.7714(7) Angstrom, b = 6.4172(2) Angstrom, c = 10.652(1) Angstrom, beta = 100.702(5)degrees, Z = 2.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 01/12/20 alle ore 11:00:57