Catalogo Articoli (Spogli Riviste)

OPAC HELP

Titolo:
Short-lived reactive formate species on NiO(111) observed by picosecond temperature jump
Autore:
Bandara, A; Kubota, J; Onda, K; Wada, A; Domen, K; Hirose, C;
Indirizzi:
Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan Tokyo Inst Technol Yokohama Kanagawa Japan 2268503 anagawa 2268503, Japan
Titolo Testata:
SURFACE SCIENCE
, volume: 435, anno: 1999,
pagine: 83 - 87
SICI:
0039-6028(19990802)435:<83:SRFSON>2.0.ZU;2-I
Fonte:
ISI
Lingua:
ENG
Soggetto:
NI(110) SURFACE; FORMIC-ACID; SFG;
Keywords:
formate; NiO(111); reactive intermediates; sum frequency generation (SFG) spectroscopy; surface chemical reaction;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
10
Recensione:
Indirizzi per estratti:
Indirizzo: Hirose, C Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, 4259 Nagatsuta,Yokohama, Kanagawa 2268503, Japan Tokyo Inst Technol 4259 Nagatsuta Yokohama Kanagawa Japan 2268503
Citazione:
A. Bandara et al., "Short-lived reactive formate species on NiO(111) observed by picosecond temperature jump", SURF SCI, 435, 1999, pp. 83-87

Abstract

The combination of an instantaneous temperature jump induced by the irradiation of picosecond laser pulses and the subsequent observation by sum-frequency generation spectroscopy enabled the identification of a short-lived reactive intermediate in the decomposition of formate on NiO(111) surface. The irradiation of 1064 nm laser pulses caused the vibrational peak at 2160 cm(-1), which is the C-D stretching mode nu(CD) of bidentate formate, to weaken and the nu(CD) of monodentate formate at 2190 cm(-1) to appear. The spectral changes recovered in 100 ps time scale but not fully above 400 K. The observations suggested that the formate in bidentate configuration transformed to monodentate formate prior to decomposition. Temperature- and time-dependent features indicated that the two types of formate were in equilibrium and the equilibrium shifted towards the monodentate form by a rapid laser-induced temperature jump of about 250-300 K. The experiment enabled us to identify short-lived species and to estimate kinetic parameters. The enthalpy difference between bidentate and monodentate formates and the activation energy for the decomposition of monodentate formate were 19+/-5 and 30+/-10 kJ/mol, respectively. (C) 1999 Elsevier Science B.V. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 26/09/20 alle ore 14:07:01