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Titolo:
Synthesis of both enantiomers of phenylglycine using (-)-sparteine
Autore:
Barberis, C; Voyer, N;
Indirizzi:
Univ Laval, Dept Chim, St Foy, PQ G1K 7P4, Canada Univ Laval St Foy PQ Canada G1K 7P4 Dept Chim, St Foy, PQ G1K 7P4, Canada
Titolo Testata:
SYNLETT
fascicolo: 7, , anno: 1999,
pagine: 1106 - 1108
SICI:
0936-5214(199907):7<1106:SOBEOP>2.0.ZU;2-A
Fonte:
ISI
Lingua:
ENG
Soggetto:
ENANTIOSELECTIVE SYNTHESIS; ELECTROPHILIC SUBSTITUTION; GENERATION; LITHIATION; REDUCTION;
Keywords:
enantioselective deprotonation; (-)-sparteine; carboxylation; silicon rearrangement; phenylglycine;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
13
Recensione:
Indirizzi per estratti:
Indirizzo: Voyer, N Univ Laval, Dept Chim, St Foy, PQ G1K 7P4, Canada Univ Laval St Foy PQ Canada G1K 7P4 , St Foy, PQ G1K 7P4, Canada
Citazione:
C. Barberis e N. Voyer, "Synthesis of both enantiomers of phenylglycine using (-)-sparteine", SYNLETT, (7), 1999, pp. 1106-1108

Abstract

The enantioselective synthesis of both enantiomers of the N-Moc phenylglycine derivatives is reported. The synthetic strategy shows the influence of N-protecting groups in the enantioselective deprotonation and carboxylationof N,N-protected benzylamine 1 using s-BuLi.(-)-sparteine complex 4 as chirality source.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 29/01/20 alle ore 19:34:05