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Titolo:
A practical method for synthesis of terminal 1,2-diols in high enantiomeric excess via oxazaborolidine-catalyzed asymmetric reduction
Autore:
Cho, BT; Chun, YS;
Indirizzi:
Hallym Univ, Dept Chem, Chunchon 200702, Kangwondo, South Korea Hallym Univ Chunchon Kangwondo South Korea 200702 Kangwondo, South Korea
Titolo Testata:
TETRAHEDRON-ASYMMETRY
fascicolo: 10, volume: 10, anno: 1999,
pagine: 1843 - 1846
SICI:
0957-4166(19990521)10:10<1843:APMFSO>2.0.ZU;2-E
Fonte:
ISI
Lingua:
ENG
Soggetto:
MOLECULAR ADDITION-COMPOUNDS; BORANE AMINE COMPLEXES; ENANTIOSELECTIVE REDUCTION; KETONES; DIHYDROXYLATION; HYDROLYSIS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
22
Recensione:
Indirizzi per estratti:
Indirizzo: Cho, BT Hallym Univ, Dept Chem, Chunchon 200702, Kangwondo, South Korea Hallym Univ Chunchon Kangwondo South Korea 200702 do, South Korea
Citazione:
B.T. Cho e Y.S. Chun, "A practical method for synthesis of terminal 1,2-diols in high enantiomeric excess via oxazaborolidine-catalyzed asymmetric reduction", TETRAHEDR-A, 10(10), 1999, pp. 1843-1846

Abstract

Asymmetric borane reduction of oc-hydroxy ketones protected with a tetrahydropyranyl (THP) group catalyzed by Corey's CBS reagent using N-phenylamine-borane complexes as the hydride source provided the corresponding terminal1,2-diols with a very high enantiomeric excess. (C) 1999 Elsevier Science Ltd. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 26/09/20 alle ore 05:20:07