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Titolo:
Dynamic control of ligand conformation: Asymmetric epoxidation using achiral (salen)manganese(III) complex
Autore:
Miura, K; Katsuki, T;
Indirizzi:
Kyushu Univ, Grad Sch Sci, Dept Mol Chem, Higashi Ku, Fukuoka 8128581, Japan Kyushu Univ Fukuoka Japan 8128581 em, Higashi Ku, Fukuoka 8128581, Japan
Titolo Testata:
SYNLETT
fascicolo: 6, , anno: 1999,
pagine: 783 - 785
SICI:
0936-5214(199906):6<783:DCOLCA>2.0.ZU;2-Q
Fonte:
ISI
Lingua:
ENG
Soggetto:
(S)-3,3'-DIMETHYL-2,2'-BIQUINOLINE N,N'-DIOXIDE; OLEFINS; CATALYST; AMINE;
Keywords:
asymmetric epoxidation; (salen)manganese(III) complex; dynamic stereocontrol;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
12
Recensione:
Indirizzi per estratti:
Indirizzo: Katsuki, T Kyushu Univ, Grad Sch Sci, Dept Mol Chem, Higashi Ku, 33 Hakozaki, Fukuoka8128581, Japan Kyushu Univ 33 Hakozaki Fukuoka Japan 8128581 ka8128581, Japan
Citazione:
K. Miura e T. Katsuki, "Dynamic control of ligand conformation: Asymmetric epoxidation using achiral (salen)manganese(III) complex", SYNLETT, (6), 1999, pp. 783-785

Abstract

High enantioselectivity and good chemical yields were realized in the epoxidation of 2,2-dimethylchromene derivatives using achiral (salen)manganese(III) complex 5 as a catalyst in the presence of axially chiral bipyridine N,N'-dioxide 4.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 15/07/20 alle ore 08:23:11